A flexible MMOF exhibiting high selectivity for CO2 over N2, CH4 and other small gases

被引：107

作者：

Zhang, Jingming ^{[1
]}

Wu, Haohan ^{[1
]}

Emge, Thomas J. ^{[1
]}

Li, Jing ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 48期

关键词：

METAL-ORGANIC FRAMEWORK; PRESSURE SWING ADSORPTION; GRAPHITIZED CARBON BLACK; COORDINATION-POLYMER; SURFACE-AREA; DIOXIDE; SORPTION; MIL-53; ISOTHERMS; MOLECULES;

D O I：

10.1039/c0cc02942d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A flexible microporous metal organic framework structure, [Zn-2(bpdc)(2)bpe]center dot 2DMF, exhibits high selectivity in adsorbing CO2 over N-2, CH4 and a number of other small gases at room temperature and low pressure.

引用

页码：9152 / 9154

页数：3

共 53 条

[1] APPARENT QUADRUPOLE-MOMENTS OF CARBON-MONOXIDE AND NITROGEN AND THEIR LIBRATIONAL MOTION IN LIQUID-STATE [J].

AMEY, RL .

JOURNAL OF PHYSICAL CHEMISTRY, 1974, 78 (19) :1968-1971

[2] Synthesis, Structure, Assembly, and Modulation of the CO2 Adsorption Properties of a Zinc-Adeninate Macrocycle [J].

An, Jihyun ;

Fiorella, Richard P. ;

Geib, Steven J. ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (24) :8401-+

[3] Porosity, surface area, surface energy, and hydrogen adsorption in nanostructured carbons [J].

Ansón, A ;

Jagiello, J ;

Parra, JB ;

Sanjuán, ML ;

Benito, AM ;

Maser, WK ;

Martínez, MT .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (40) :15820-15826

[4] Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification [J].

Bae, Youn-Sang ;

Farha, Omar K. ;

Hupp, Joseph T. ;

Snurr, Randall Q. .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (15) :2131-2134

[5] Control of porosity geometry in amino acid derived nanoporous materials [J].

Barrio, Jorge Perez ;

Rebilly, Jean-Noel ;

Carter, Benjamin ;

Bradshaw, Darren ;

Bacsa, John ;

Ganin, Alexey Y. ;

Park, Hyunsoo ;

Trewin, Abbie ;

Vaidhyanathan, Ramanathan ;

Cooper, Andrew I. ;

Warren, John E. ;

Rosseinsky, Matthew J. .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (15) :4521-4532

[6] Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47 [J].

Bourrelly, S ;

Llewellyn, PL ;

Serre, C ;

Millange, F ;

Loiseau, T ;

Férey, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) :13519-13521

[7] Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores [J].

Caskey, Stephen R. ;

Wong-Foy, Antek G. ;

Matzger, Adam J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10870-+

[8] Removal of carbon dioxide from natural gas by vacuum pressure swing adsorption [J].

Cavenati, Simone ;

Grande, Carlos A. ;

Rodrigues, Alirio E. .

ENERGY & FUELS, 2006, 20 (06) :2648-2659

[9] A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules [J].

Chen, Banglin ;

Ma, Shengqian ;

Hurtado, Eric J. ;

Lobkovsky, Emil B. ;

Zhou, Hong-Cai .

INORGANIC CHEMISTRY, 2007, 46 (21) :8490-8492

[10] Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules [J].

Chen, Banglin ;

Ma, Shengqian ;

Zapata, Fatima ;

Fronczek, Frank R. ;

Lobkovsky, Emil B. ;

Zhou, Hong-Cai .

INORGANIC CHEMISTRY, 2007, 46 (04) :1233-1236

← 1 2 3 4 5 6 →