Convenient synthesis of optically active 1,2-diol monosulfonates and terminal epoxides via oxazaborolidine-catalyzed asymmetric borane reduction of α-sulfonyloxy ketones

被引：29

作者：

Cho, BT ^{[1
]}

Yang, WK ^{[1
]}

Choi, OK ^{[1
]}

机构：

[1] Hallym Univ, Dept Chem, Chunchon 200702, Kangwondo, South Korea

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2001年 / 10期

关键词：

D O I：

10.1039/b010155i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A very convenient asymmetric synthesis of 1,2-diol monosulfonates and terminal epoxides with high optical purity via oxazaborolidine-catalyzed asymmetric borane reduction of alpha -sulfonyloxy ketones using N-ethyl-N-isopropylaniline-borane complex as borane carrier has been developed.

引用

页码：1204 / 1211

页数：8

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