Evidence for why tri(ethylene oxide) functionalized Si-C linked monolayers on Si(111) have inferior protein antifouling properties relative to the equivalent alkanethiol monolayers assembled on gold

被引：16

作者：

Böcking, T

Gal, M

Gaus, K

Gooding, JJ ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

[2] Univ New S Wales, Sch Phys, Sydney, NSW 2052, Australia

[3] Univ New S Wales, Sch Med Sci, Ctr Vasc Res, Sydney, NSW 2052, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2005年 / 58卷 / 09期

关键词：

D O I：

10.1071/CH05121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High quality methoxy-terminated monolayers containing a tri(ethylene oxide) moiety were formed on Si(111)-H surfaces in thermal hydrosilylation reactions. X-ray photoelectron spectroscopy, contact angle, and X-ray reflectivity measurements suggested that the suboptimal protein anti-fouling properties of these Si-C linked monolayers were due to a reduced lateral packing density of the chains resulting in a disordered layer with insufficient internal and external hydrophilicity.

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页码：660 / 663

页数：4

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