Addition of carbamoylsilanes to electrophilically substituted alkenes.: Preparation of β-functionalized tertiary amides

被引：46

作者：

Cunico, RF ^{[1
]}

Motta, AR ^{[1
]}

机构：

[1] No Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 05期

关键词：

D O I：

10.1021/ol040066p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Si-C bond of N, N-dimethylcarbamoylsilanes added regiospecifically to the C=C bond of electrophilically functionalized alkenes to afford beta-silyl-beta-functionalized amides. Carbonyl addition products were formed when hindered alkenic esters were used.

引用

页码：771 / 774

页数：4

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