Coordination and Dehydrogenation of Amine-Boranes at Metal Centers

被引：210

作者：

Alcaraz, Gilles ^{[1
,2
]}

Sabo-Etienne, Sylviane ^{[1
,2
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

[2] Univ Toulouse, UPS, INPT, F-31077 Toulouse, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 40期

关键词：

amine-boranes; B-H activation; dehydrogenation; hydrogen storage; sigma-borane complexes; REVERSIBLE HYDROGEN RELEASE; BORON-NITROGEN BONDS; LEWIS BASE ADDUCTS; AMMONIA-BORANE; SIGMA-BORANE; CATALYZED DEHYDROGENATION; RUTHENIUM COMPLEXES; BORYL COMPLEXES; AMINOBORANE COMPLEXES; DIMETHYLAMINE-BORANE;

D O I：

10.1002/anie.201000898

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Debaser: Key elementary steps in the activation of H3B-NH 3 and derivatives upon coordination to a metal fragment have been identified. Recent results in the metal-induced dehydrogenation of amine-boranes show the importance of the B-H bond-activation step. Isolated complexes show unprecedented amine-borane bonding modes and H2BNH2 trapping on a metal center thanks to a bis(σ-B-H) mode. © 2010 Wiley-VCH Verlag GmbH & Co. KgaA, Weinheim.

引用

收藏

页码：7170 / 7179

页数：10

相关论文

共 97 条

[1]

ALCARAZ G, UNPUB

[2] NMR: A good tool to ascertain σ-silane or σ-borane formulations? [J].

Alcaraz, Gilles ;

Sabo-Etienne, Sylviane .

COORDINATION CHEMISTRY REVIEWS, 2008, 252 (21-22) :2395-2409

[3] A terminal borylene ruthenium complex: From B-H activation to reversible hydrogen release [J].

Alcaraz, Gilles ;

Helmstedt, Ulrike ;

Clot, Eric ;

Vendier, Laure ;

Sabo-Etienne, Sylviane .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (39) :12878-+

[4] Mesitylborane as a bis(σ-B-H) ligand:: An unprecedented bonding mode to a metal center [J].

Alcaraz, Gilles ;

Clot, Eric ;

Helmstedt, Ulrike ;

Vendier, Laure ;

Sabo-Etienne, Sylviane .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (28) :8704-+

[5] Ruthenium Bis(σ-B-H) Aminoborane Complexes from Dehydrogenation of Amine-Boranes: Trapping of H2B-NH2 [J].

Alcaraz, Gilles ;

Vendier, Laure ;

Clot, Eric ;

Sabo-Etienne, Sylviane .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (05) :918-920

[6] Bis σ-Bond Dihydrogen and Borane Ruthenium Complexes: Bonding Nature, Catalytic Applications, and Reversible Hydrogen Release [J].

Alcaraz, Gilles ;

Grellier, Mary ;

Sabo-Etienne, Sylviane .

ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (10) :1640-1649

[7] REACTIONS OF THEOXYLBORANE WITH (PHOSPHINE)RHODIUM HYDRIDE, ALKYL, AND ALLYL COMPLEXES [J].

BAKER, RT ;

OVENALL, DW ;

HARLOW, RL ;

WESTCOTT, SA ;

TAYLOR, NJ ;

MARDER, TB .

ORGANOMETALLICS, 1990, 9 (12) :3028-3030

[8] Hydroborations catalysed by transition metal complexes [J].

Beletskaya, I ;

Pelter, A .

TETRAHEDRON, 1997, 53 (14) :4957-5026

[9] Ruthenium-Catalyzed Dehydrogenation of Ammonia Boranes [J].

Blaquiere, Nicole ;

Diallo-Garcia, Sarah ;

Gorelsky, Serge I. ;

Black, Daniel A. ;

Fagnou, Keith .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (43) :14034-+

[10] Access to ruthenium(0) carbonyl complexes via dehydrogenation of a tricyclopentylphosphine ligand and decarbonylation of alcohols [J].

Bolton, Paul D. ;

Grellier, Mary ;

Vautravers, Nicolas ;

Vendier, Laure ;

Sabo-Etienne, Sylviane .

ORGANOMETALLICS, 2008, 27 (19) :5088-5093

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