Pd-Catalyzed Oxidative Cross-Coupling of Perfluoroarenes with Aromatic Heterocycles

被引：271

作者：

He, Chun-Yang ^{[1
]}

Fan, Shilu ^{[1
]}

Zhang, Xingang ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 37期

关键词：

C-H FUNCTIONALIZATION; THIN-FILM TRANSISTORS; DIRECT ARYLATION; ORGANIC SEMICONDUCTORS; ARENES; OLIGOFLUOROBENZENES; OLIGOTHIOPHENES; DERIVATIVES; ACTIVATION; MECHANISM;

D O I：

10.1021/ja106046p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A straightforward and practical method for direct Pd(OAc)(2)-catalyzed oxidative cross-coupling of electron-deficient perfluoroarenes with aromatic heterocycles has been developed. Because of its low catalyst loading (2.5 mol %), high reaction efficiency, good chemo- and regioselectivity, and excellent functional-group compatibility, this protocol provides a useful and operationally simple access to perfluoroarene thiophene structures of interest in functional materials for electronic devices.

引用

页码：12850 / 12852

页数：3

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