Modular chemical tools for advanced macromolecular engineering

被引：92

作者：

Lutz, Jean-Francois ^{[1
]}

Schlaad, Helmut ^{[2
]}

机构：

[1] Fraunhofer Inst Appl Polymer Res, Res Grp Nanotechnol Life Sci, D-14476 Potsdam, Germany

[2] Max Planck Inst Colloids & Interfaces, Colloid Dept, D-14424 Potsdam, Germany

来源：

POLYMER | 2008年 / 49卷 / 04期

关键词：

living/controlled polymerizations; click" chemistry; bio-hybrids;

D O I：

10.1016/j.polymer.2007.10.045

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Contemporary polymer science requires, more than ever, simple and efficient chemical reactions for constructing complex macromolecular or supramolecular structures. The present feature article highlights our recent efforts to develop modular synthetic platforms in macromolecular synthesis. As examples, the macromolecular engineering possibilities of two "click" reactions (i) the copper-catalyzed cycloaddition of azides and terminal alkynes and (ii) the radical addition of mercaptans onto vinyl double bonds are discussed in detail herein. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：817 / 824

页数：8

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