Symmetry Switch of Cobalt Ferrocyanide Framework by Alkaline Cation Exchange

被引：69

作者：

Matsuda, Tomoyuki ^{[1
]}

Kim, Jungeun ^{[2
]}

Moritomo, Yutaka ^{[1
]}

机构：

[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

[2] JASRI SPring 8, Sayo, Hyogo 6795198, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 35期

关键词：

PRUSSIAN BLUE ANALOGS; MAGNETIC-ORDERING TEMPERATURE; MOLECULE-BASED MAGNET; ROOM-TEMPERATURE; COORDINATION POLYMERS; POLE INVERSION; IRON CYANIDE; DEGREES-C; NI; HEXACYANOFERRATE;

D O I：

10.1021/ja105482k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We observed a reversible symmetry switch of a cobalt ferrocyanide framework by the alkaline cation exchange and resultant control of the optical properties at room temperature.

引用

收藏

页码：12206 / 12207

页数：2

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