Multilayer nanoassembly of Sn-nanopillar arrays sandwiched between graphene layers for high-capacity lithium storage

被引：203

作者：

Ji, Liwen ^{[1
]}

Tan, Zhongkui ^{[1
]}

Kuykendall, Tevye ^{[1
]}

An, Eun Ji ^{[1
]}

Fu, Yanbao ^{[2
]}

Battaglia, Vincent ^{[2
]}

Zhang, Yuegang ^{[1
]}

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Mol Foundry, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Adv Energy Technol Dept, Berkeley, CA 94720 USA

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2011年 / 4卷 / 09期

关键词：

ION BATTERIES; ANODE MATERIAL; HOLLOW CARBON; SECONDARY BATTERIES; TIN-NANOPARTICLES; FILM FORMATION; PERFORMANCE; NANOFIBERS; ELECTRODE; ENCAPSULATION;

D O I：

10.1039/c1ee01592c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sn nanopillar arrays embedded between graphene sheets were assembled using a conventional film deposition and annealing process. The as-formed three-dimensional (3D) multilayered nanostructure was directly used as an anode material for rechargeable lithium-ion batteries without adding any polymer binder and carbon black. Electrochemical measurements showed very high reversible capacity and excellent cycling performance at a current density as high as 5 A g(-1). These results demonstrated that nanocomposite materials with highly functional 1D and 2D components can be synthesized by employing conventional top-down manufacturing methods and self-assembly principles.

引用

页码：3611 / 3616

页数：6

共 51 条

[1] High rate capability pure Sn-based nano-architectured electrode assembly for rechargeable lithium batteries [J].

Bazin, L. ;

Mitra, S. ;

Taberna, P. L. ;

Poizot, P. ;

Gressier, M. ;

Menu, M. J. ;

Barnabe, A. ;

Simon, P. ;

Tarascon, J. -M. .

JOURNAL OF POWER SOURCES, 2009, 188 (02) :578-582

[2] SEI film formation on highly crystalline graphitic materials in lithium-ion batteries [J].

Buqa, H ;

Würsig, A ;

Vetter, J ;

Spahr, ME ;

Krumeich, F ;

Novák, P .

JOURNAL OF POWER SOURCES, 2006, 153 (02) :385-390

[3] Better lithium-ion batteries with nanocable-like electrode materials [J].

Cao, Fei-Fei ;

Guo, Yu-Guo ;

Wan, Li-Jun .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (05) :1634-1642

[4] High-performance lithium battery anodes using silicon nanowires [J].

Chan, Candace K. ;

Peng, Hailin ;

Liu, Gao ;

McIlwrath, Kevin ;

Zhang, Xiao Feng ;

Huggins, Robert A. ;

Cui, Yi .

NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35

[5] A one-step approach towards carbon-encapsulated hollow tin nanoparticles and their application in lithium batteries [J].

Cui, Guanglei ;

Hu, Yong-Sheng ;

Zhi, Linjie ;

Wu, Dongqing ;

Lieberwirth, Ingo ;

Maier, Joachim ;

Muellen, Klaus .

SMALL, 2007, 3 (12) :2066-2069

[6] Direct fabrication of double-rough chestnut-like multifunctional Sn@C composites on copper foil: lotus effect and lithium ion storage properties [J].

Deng, Da ;

Lee, Jim Yang .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (37) :8045-8049

[7] Green energy storage materials: Nanostructured TiO2 and Sn-based anodes for lithium-ion batteries [J].

Deng, Da ;

Kim, Min Gyu ;

Lee, Jim Yang ;

Cho, Jaephil .

ENERGY & ENVIRONMENTAL SCIENCE, 2009, 2 (08) :818-837

[8] Reversible Storage of Lithium in a Rambutan-Like Tin-Carbon Electrode [J].

Deng, Da ;

Lee, Jim Yang .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (09) :1660-1663

[9] Nanostructured Sn-C composite as an advanced anode material in high-performance lithium-ion batteries [J].

Derrien, Gaelle ;

Hassoun, Jusef ;

Panero, Stefania ;

Scrosati, Bruno .

ADVANCED MATERIALS, 2007, 19 (17) :2336-+

[10] High-yield production of graphene by liquid-phase exfoliation of graphite [J].

Hernandez, Yenny ;

Nicolosi, Valeria ;

Lotya, Mustafa ;

Blighe, Fiona M. ;

Sun, Zhenyu ;

De, Sukanta ;

McGovern, I. T. ;

Holland, Brendan ;

Byrne, Michele ;

Gun'ko, Yurii K. ;

Boland, John J. ;

Niraj, Peter ;

Duesberg, Georg ;

Krishnamurthy, Satheesh ;

Goodhue, Robbie ;

Hutchison, John ;

Scardaci, Vittorio ;

Ferrari, Andrea C. ;

Coleman, Jonathan N. .

NATURE NANOTECHNOLOGY, 2008, 3 (09) :563-568

← 1 2 3 4 5 6 →