Intense ultraviolet photoluminescence from amorphous Si:O:C films prepared by liquid-solution-phase technique

被引:13
作者
Fu, ZP
Li, M
Yang, BF [1 ]
Liu, RC
机构
[1] Univ Sci & Technol China, Acad Sinica, Struct Res Lab, Anhua 230026, Peoples R China
[2] Univ Sci & Technol China, Acad Sinica, Dept Mat Sci & Engn, Anhua 230026, Peoples R China
[3] Univ Sci & Technol China, Acad Sinica, Internal Frict & Detects Solid Lab, Anhua 230026, Peoples R China
关键词
photoluminescence; liquid-solution-phase; Si/O/C film;
D O I
10.1016/S0040-6090(01)00868-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Intense ultraviolet (W) photoluminescence (PL) was observed at room temperature from amorphous Si:O:C films synthesized at 200, 300, 400 degreesC by the liquid-solution-phase (LSP) method. The intensity was as strong as that of visible emission band from porous silicon. In all the films, a band existed, centered at 340 mn, while a shoulder band centered at 380 nm was observed from the films deposited at 400 degreesC. By analyzing the PL and photoluminescence excitation (PLE) spectra, Fourier-transform infrared (FTIR) absorption, X-ray photoelectronic spectroscopy (XPS) and X-ray diffraction (XRD), we suggest that the photoluminescence peak at 340 nm originates from the defects in silicon oxide network, while the peak at 380 nm may be related to Si-C and Si-Si bonds in the samples. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:12 / 15
页数:4
相关论文
共 18 条
[1]   Carbon incorporation in Si1-yCy alloys grown by molecular beam epitaxy using a single silicon-graphite source [J].
Dashiell, MW ;
Kulik, LV ;
Hits, D ;
Kolodzey, J ;
Watson, G .
APPLIED PHYSICS LETTERS, 1998, 72 (07) :833-835
[2]   ANALYSIS OF SURFACE OXIDES OF GAS-EVAPORATED SI SMALL PARTICLES WITH INFRARED-SPECTROSCOPY, HIGH-RESOLUTION ELECTRON-MICROSCOPY, AND X-RAY PHOTOEMISSION SPECTROSCOPY [J].
HAYASHI, S ;
TANIMOTO, S ;
YAMAMOTO, K .
JOURNAL OF APPLIED PHYSICS, 1990, 68 (10) :5300-5308
[3]   A LIQUID-SOLUTION-PHASE SYNTHESIS OF CRYSTALLINE SILICON [J].
HEATH, JR .
SCIENCE, 1992, 258 (5085) :1131-1133
[4]   SiC formation at the interface of polyimide Langmuir-Blodgett film and silicon [J].
Ji, MR ;
Zhu, JS ;
Ma, MS ;
Wu, JX ;
Liu, XM ;
Jin, BK ;
Yang, BF ;
He, PS ;
Ruan, YZ .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (04) :2471-2474
[5]   Room-temperature visible photoluminescence from silicon-rich oxide layers deposited by an electron cyclotron resonance plasma source [J].
Kim, K ;
Suh, MS ;
Kim, TS ;
Youn, CJ ;
Suh, EK ;
Shin, YJ ;
Lee, KB ;
Lee, HJ ;
An, MH ;
Lee, HJ ;
Ryu, H .
APPLIED PHYSICS LETTERS, 1996, 69 (25) :3908-3910
[6]   A reduction-pyrolysis-catalysis synthesis of diamond [J].
Li, YD ;
Qian, YT ;
Liao, HW ;
Ding, Y ;
Yang, L ;
Xu, CY ;
Li, FQ ;
Zhou, G .
SCIENCE, 1998, 281 (5374) :246-247
[7]   Stable blue-green and ultraviolet photoluminescence from silicon carbide on porous silicon [J].
Liu, RC ;
Yang, BF ;
Fu, ZP ;
He, PS ;
Ruan, YZ .
SOLID STATE COMMUNICATIONS, 1998, 106 (04) :211-214
[8]   Red-green-blue light emission from hydrogenated amorphous silicon carbide films prepared by using organic compound xylene as carbon source [J].
Ma, TF ;
Xu, J ;
Chen, KJ ;
Du, JF ;
Li, W ;
Huang, XF .
APPLIED PHYSICS LETTERS, 1998, 72 (01) :13-15
[9]   SILICON DIOXIDE THIN-FILMS PREPARED BY CHEMICAL-VAPOR-DEPOSITION FROM TETRAKIS(DIETHYLAMINO)SILANE AND OZONE [J].
MARUYAMA, T ;
OHTANI, S .
APPLIED PHYSICS LETTERS, 1994, 64 (21) :2800-2802
[10]   LUMINESCENCE FROM A SI-SIO2 NANOCLUSTER-LIKE STRUCTURE PREPARED BY LASER-ABLATION [J].
MOVTCHAN, IA ;
DREYFUS, RW ;
MARINE, W ;
SENTIS, M ;
AUTRIC, M ;
LELAY, G ;
MERK, N .
THIN SOLID FILMS, 1995, 255 (1-2) :286-289