Coordination polymers from M(hfac)2 [M = CuII, MnII] and 4,4′-dipyridyldisulfide

被引：67

作者：

Horikoshi, R ^{[1
]}

Mochida, T ^{[1
]}

Moriyama, H ^{[1
]}

机构：

[1] Toho Univ, Fac Sci, Dept Chem, Funabashi, Chiba 2748510, Japan

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 10期

关键词：

D O I：

10.1021/ic001180g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of M(hfac)(2) with a -S-S- bridged bidentate ligand 4-PDS (=4,4'-dipyridyl disulfide) afforded 1:1 coordination polymers 4-PDS . Cu(Hfac)(2) (I) and 4-PDS . Mn(hfac)2 (2). The Cu(II) ions in 1 are linked by the twisted molecules of 4-PDS, forming a one-dimensional helical chain structure, the N-donor ligands of 4-PDS occupying the cis positions around the Cu(II) ion. The structure of 2 consists of zigzag infinite chains, the N-donor ligands occupying the trans positions around the metal center.

引用

页码：2430 / +

页数：5

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