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Spin canting and metamagnetism in a 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II)-coordination-polymer sheets

被引：299
作者：
Zeng, MH
Zhang, WX
Sun, XZ
Chen, XM [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
[2] GuangXi Normal Univ, Res Inst Bioorgan Chem, Dept Chem & Chem Engn, Guilin 541004, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 20期
关键词：
cobalt; magnetic properties; metamagnets; N ligands; O ligands;
D O I：
10.1002/anie.200462463
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two different types of coordination sheets made up of CoII ions, 3-hydroxypicolinate, and 4,4′-bipyridine interpenetrate to form a unique molecular-based magnetic material (see picture). This material displays a low-field metamagnetic transition and spin-canted behavior. (Figure Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码：3079 / 3082
页数：4
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