Electronic Junction Control in a Nanotube-Semiconductor Schottky Junction Solar Cell

被引:128
作者
Wadhwa, Pooja [1 ]
Liu, Bo [1 ]
McCarthy, Mitchell A.
Wu, Zhuangchun [1 ]
Rinzler, Andrew G. [1 ]
机构
[1] Univ Florida, Dept Phys, Gainesville, FL 32611 USA
基金
美国国家科学基金会;
关键词
Schottky junction; solar cell; electronic gating; carbon nanotubes; crystalline silicon; MOLECULAR MONOLAYERS; SILICON; SURFACE; TRANSISTORS; FILMS;
D O I
10.1021/nl103128a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We exploit the low density of electronic states in single wall carbon nanotubes to demonstrate active, electronic modulation of their Fermi level offset relative to n-type silicon in a nanotube-Si (metal-semiconductor) Schottky junction solar cell. Electronic modulation of the Fermi level offset, the junction interface dipole and a field developed across the depletion layer modifies the built-in potential in the device and its power generation characteristics. As produced (before modulation). devices exhibit similar to 8.5% power conversion efficiency (PCE). With active modulation the PCE is continuously and reversibly changed from 4 to 11 %.
引用
收藏
页码:5001 / 5005
页数:5
相关论文
共 16 条
[1]   SURFACE STATES AND BARRIER HEIGHT OF METAL-SEMICONDUCTOR SYSTEMS [J].
COWLEY, AM ;
SZE, SM .
JOURNAL OF APPLIED PHYSICS, 1965, 36 (10) :3212-&
[2]   Controlling semiconductor/metal junction barriers by incomplete, nonideal molecular monolayers [J].
Haick, Hossam ;
Ambrico, Marianna ;
Ligonzo, Teresa ;
Tung, Raymond T. ;
Cahen, David .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (21) :6854-6869
[3]   Spectroscopic investigations of hydrogen termination, oxide coverage, roughness, and surface state density of silicon during native oxidation in air [J].
Henrion, W ;
Rebien, M ;
Angermann, H ;
Röseler, A .
APPLIED SURFACE SCIENCE, 2002, 202 (3-4) :199-205
[4]   Molecularly controlled metal-semiconductor junctions on silicon surface: A dipole effect [J].
Hiremath, R. K. ;
Rabinal, M. K. ;
Mulimani, B. G. ;
Khazi, I. M. .
LANGMUIR, 2008, 24 (19) :11300-11306
[5]   Nanotube-Silicon Heterojunction Solar Cells [J].
Jia, Yi ;
Wei, Jinquan ;
Wang, Kunlin ;
Cao, Anyuan ;
Shu, Qinke ;
Gui, Xuchun ;
Zhu, Yanqiu ;
Zhuang, Daming ;
Zhang, Gong ;
Ma, Beibei ;
Wang, Liduo ;
Liu, Wenjin ;
Wang, Zhicheng ;
Luo, Jianbin ;
Wu, Dehai .
ADVANCED MATERIALS, 2008, 20 (23) :4594-4598
[6]   Large-scale pattern growth of graphene films for stretchable transparent electrodes [J].
Kim, Keun Soo ;
Zhao, Yue ;
Jang, Houk ;
Lee, Sang Yoon ;
Kim, Jong Min ;
Kim, Kwang S. ;
Ahn, Jong-Hyun ;
Kim, Philip ;
Choi, Jae-Young ;
Hong, Byung Hee .
NATURE, 2009, 457 (7230) :706-710
[7]   Graphene-On-Silicon Schottky Junction Solar Cells [J].
Li, Xinming ;
Zhu, Hongwei ;
Wang, Kunlin ;
Cao, Anyuan ;
Wei, Jinquan ;
Li, Chunyan ;
Jia, Yi ;
Li, Zhen ;
Li, Xiao ;
Wu, Dehai .
ADVANCED MATERIALS, 2010, 22 (25) :2743-+
[8]   Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils [J].
Li, Xuesong ;
Cai, Weiwei ;
An, Jinho ;
Kim, Seyoung ;
Nah, Junghyo ;
Yang, Dongxing ;
Piner, Richard ;
Velamakanni, Aruna ;
Jung, Inhwa ;
Tutuc, Emanuel ;
Banerjee, Sanjay K. ;
Colombo, Luigi ;
Ruoff, Rodney S. .
SCIENCE, 2009, 324 (5932) :1312-1314
[9]   Carbon-Nanotube-Enabled Vertical Field Effect and Light-Emitting Transistors [J].
Liu, Bo ;
McCarthy, Mitchell A. ;
Yoon, Youngki ;
Kim, Do Young ;
Wu, Zhuangchun ;
So, Franky ;
Holloway, Paul H. ;
Reynolds, John R. ;
Guo, Jing ;
Rinzler, Andrew G. .
ADVANCED MATERIALS, 2008, 20 (19) :3605-+
[10]   A tunable diode based on an inorganic semiconductor vertical bar conjugated polymer interface [J].
Lonergan, MC .
SCIENCE, 1997, 278 (5346) :2103-2106