Studies toward the total synthesis of nakiterpiosin: construction of the CDE ring system by a transannular Diels-Alder strategy

被引：17

作者：

Ito, Tomonori

Ito, Masahiro

Arimoto, Hirokazu ^{[1
]}

Takamura, Hiroyoshi

Uemura, Daisuke

机构：

[1] Nagoya Univ, Grad Sch Sci, Nagoya, Aichi 4648602, Japan

[2] Tohoku Univ, Grad Sch Life Sci, Sendai, Miyagi 9818555, Japan

[3] Nagoya Univ, Inst Adv Res, Nagoya, Aichi 4648602, Japan

来源：

TETRAHEDRON LETTERS | 2007年 / 48卷 / 31期

关键词：

nakiterpiosin; synthetic study; transannular Diels-Alder reaction;

D O I：

10.1016/j.tetlet.2007.05.174

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The transarmular Diels-Alder (TADA) reaction was applied to the synthesis of the CDE ring system of nakiterpiosin (1). Tetracyclic compound 25 may be a key intermediate in the total synthesis of 1. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：5465 / 5469

页数：5

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