An Evaluation of UiO-66 for Gas-Based Applications

被引：206

作者：

Wiersum, Andrew D. ^{[1
,2
,3
]}

Soubeyrand-Lenoir, Estelle ^{[1
,2
,3
]}

Yang, Qingyuan ^{[4
]}

Moulin, Beatrice ^{[5
]}

Guillerm, Vincent ^{[6
]}

Ben Yahia, Mouna ^{[4
]}

Bourrelly, Sandrine ^{[1
,2
,3
]}

Vimont, Alexandre ^{[5
]}

Miller, Stuart ^{[6
]}

Vagner, Christelle ^{[1
,2
,3
]}

Daturi, Marco ^{[5
]}

Clet, Guillaume ^{[5
]}

Serre, Christian ^{[6
]}

Maurin, Guillaume ^{[4
]}

Llewellyn, Philip L. ^{[1
,2
,3
]}

机构：

[1] Univ Aix Marseille 1, CNRS, UMR 6264, Ctr St Jerome,Lab Chim Provence, F-13397 Marseille 20, France

[2] Univ Aix Marseille 2, CNRS, UMR 6264, Ctr St Jerome,Lab Chim Provence, F-13397 Marseille 20, France

[3] Univ Aix Marseille 3, CNRS, UMR 6264, Ctr St Jerome,Lab Chim Provence, F-13397 Marseille 20, France

[4] Univ Montpellier 2, CNRS, UMR 5253, Inst Charles Gerhardt Montpellier,ENSCM, F-34095 Montpellier 05, France

[5] Univ Caen, CNRS, ENSICAEN, Catalyse & Spectrochim Lab, F-14050 Caen, France

[6] Univ Versailles St Quentin Yvelines, CNRS, Inst Lavoisier CNRS 8180, F-78035 Versailles, France

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2011年 / 6卷 / 12期

关键词：

adsorption; calorimetry; density functional calculations; metal-organic frameworks; X-ray diffraction; METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; SURFACE CHARACTERIZATION; ADSORPTION-ISOTHERMS; XYLENE ISOMERS; POROUS SOLIDS; ZIRCONIA; CH4; CO2; SELECTIVITY;

D O I：

10.1002/asia.201100201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In addition to its high thermal stability, repetitive hydration/dehydration tests have revealed that the porous zirconium terephthalate UiO-66 switches reversibly between its dehydroxylated and hydroxylated versions. The structure of its dehydroxylated form has thus been elucidated by coupling molecular simulations and X-ray powder diffraction data. Infrared measurements have shown that relatively weak acid sites are available while microcalorimetry combined with Monte Carlo simulations emphasize moderate interactions between the UiO-66 surface and a wide range of guest molecules including CH4, CO, and CO2. These properties, in conjunction with its significant adsorption capacity, make UiO-66 of interest for its further evaluation for CO2 recovery in industrial applications. This global approach suggests a strategy for the evaluation of metalorganic frameworks for gas-based applications.

引用

页码：3270 / 3280

页数：11

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