A new reducing agent to prepare single-layer, high-quality reduced graphene oxide for device applications

被引:98
作者
Mao, Shun [1 ]
Yu, Kehan [1 ]
Cui, Shumao [1 ]
Bo, Zheng [1 ]
Lu, Ganhua [1 ]
Chen, Junhong [1 ]
机构
[1] Univ Wisconsin, Dept Mech Engn, Milwaukee, WI 53211 USA
基金
美国国家科学基金会;
关键词
EPITAXIAL GRAPHENE; GRAPHITE OXIDE; REDUCTION; ROUTE; FILMS;
D O I
10.1039/c1nr10270b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report on a novel, efficient, and one-step approach to prepare single-layer reduced graphene oxide (RGO) suspensions and films using hydroxylamine hydrochloride. The effective chemical reduction of GO was evidenced by a significant increase in the C/O ratio and five orders of magnitude decrease in the GO resistance. Field-effect transistor gas sensors were fabricated using as-produced RGO sheets and the resulting sensor exhibited a fast response and a high sensitivity to low-concentration target gases at room temperature.
引用
收藏
页码:2849 / 2853
页数:5
相关论文
共 38 条
[31]   Formation of Graphene Features from Direct Laser-Induced Reduction of Graphite Oxide [J].
Sokolov, Denis A. ;
Shepperd, Kristin R. ;
Orlando, Thomas M. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (18) :2633-2636
[32]   Highly Efficient Restoration of Graphitic Structure in Graphene Oxide Using Alcohol Vapors [J].
Su, Ching-Yuan ;
Xu, Yanping ;
Zhang, Wenjing ;
Zhao, Jianwen ;
Liu, Aiping ;
Tang, Xiaohong ;
Tsai, Chuen-Horng ;
Huang, Yizhong ;
Li, Lain-Jong .
ACS NANO, 2010, 4 (09) :5285-5292
[33]   Epitaxial graphene on ruthenium [J].
Sutter, Peter W. ;
Flege, Jan-Ingo ;
Sutter, Eli A. .
NATURE MATERIALS, 2008, 7 (05) :406-411
[34]   High-throughput solution processing of large-scale graphene [J].
Tung, Vincent C. ;
Allen, Matthew J. ;
Yang, Yang ;
Kaner, Richard B. .
NATURE NANOTECHNOLOGY, 2009, 4 (01) :25-29
[35]   Production of graphene from graphite oxide using urea as expansion-reduction agent [J].
Wakeland, Stephen ;
Martinez, Ricardo ;
Grey, John K. ;
Luhrs, Claudia C. .
CARBON, 2010, 48 (12) :3463-3470
[36]   Facile synthesis and characterization of graphene nanosheets [J].
Wang, Guoxiu ;
Yang, Juan ;
Park, Jinsoo ;
Gou, Xinglong ;
Wang, Bei ;
Liu, Hao ;
Yao, Jane .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (22) :8192-8195
[37]   Nanoscale Tunable Reduction of Graphene Oxide for Graphene Electronics [J].
Wei, Zhongqing ;
Wang, Debin ;
Kim, Suenne ;
Kim, Soo-Young ;
Hu, Yike ;
Yakes, Michael K. ;
Laracuente, Arnaldo R. ;
Dai, Zhenting ;
Marder, Seth R. ;
Berger, Claire ;
King, William P. ;
de Heer, Walter A. ;
Sheehan, Paul E. ;
Riedo, Elisa .
SCIENCE, 2010, 328 (5984) :1373-1376
[38]   Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy [J].
Yang, Dongxing ;
Velamakanni, Aruna ;
Bozoklu, Guelay ;
Park, Sungjin ;
Stoller, Meryl ;
Piner, Richard D. ;
Stankovich, Sasha ;
Jung, Inhwa ;
Field, Daniel A. ;
Ventrice, Carl A., Jr. ;
Ruoff, Rodney S. .
CARBON, 2009, 47 (01) :145-152