Quasi-2D Cu2S Crystals on Graphene: In-situ Growth and ab-initio Calculations

被引：25

作者：

Ben Romdhane, Ferdaous ^{[1
]}

Cretu, Ovidiu ^{[2
]}

Debbichi, Lamjed ^{[3
]}

Eriksson, Olle ^{[4
]}

Lebegue, Sebastien ^{[3
]}

Banhart, Florian ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, UMR 7504, Inst Phys & Chim Mat, F-67034 Strasbourg, France

[2] Natl Inst Adv Ind Sci & Technol, Nanotube Res Ctr, Tsukuba, Ibaraki 3058565, Japan

[3] Univ Lorraine, Lab Cristallog Resonance Magnet & Modelisat CRM2, CNRS, UMR 7036,Inst Jean Barriol, F-54506 Vandoeuvre Les Nancy, France

[4] Uppsala Univ, Dept Phys & Astron, SE-75120 Uppsala, Sweden

来源：

SMALL | 2015年 / 11卷 / 11期

基金：

瑞典研究理事会; 欧洲研究理事会;

关键词：

MOLECULAR-DYNAMICS; GREENS-FUNCTION; CUS; TRANSITION; NANORODS;

D O I：

10.1002/smll.201400444

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two-dimensional crystals of beta-copper sulfide are synthesized in an in-situ electron microscopy experiment. Copper crystals are deposited on an amorphous carbon film containing sulfur. The carbon film graphitizes upon heating and electron irradiation and allows the reaction of Cu and S towards two-dimensional Cu2S crystals. These are energetically favourable and bonded via van der Waals interactions to the graphitic substrate. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA.

引用

页码：1253 / 1257

页数：5

共 25 条

[1]

Belov N. V., 1946, DOKL AKAD NAUK SSSR, V548, P717

[2] Tkatchenko-Scheffler van der Waals correction method with and without self-consistent screening applied to solids [J].

Bucko, Tomas ;

Lebegue, S. ;

Hafner, Juergen ;

Angyan, J. G. .

PHYSICAL REVIEW B, 2013, 87 (06)

[3] Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene [J].

Butler, Sheneve Z. ;

Hollen, Shawna M. ;

Cao, Linyou ;

Cui, Yi ;

Gupta, Jay A. ;

Gutierrez, Humberto R. ;

Heinz, Tony F. ;

Hong, Seung Sae ;

Huang, Jiaxing ;

Ismach, Ariel F. ;

Johnston-Halperin, Ezekiel ;

Kuno, Masaru ;

Plashnitsa, Vladimir V. ;

Robinson, Richard D. ;

Ruoff, Rodney S. ;

Salahuddin, Sayeef ;

Shan, Jie ;

Shi, Li ;

Spencer, Michael G. ;

Terrones, Mauricio ;

Windl, Wolfgang ;

Goldberger, Joshua E. .

ACS NANO, 2013, 7 (04) :2898-2926

[4] Van der Waals heterostructures [J].

Geim, A. K. ;

Grigorieva, I. V. .

NATURE, 2013, 499 (7459) :419-425

[5] NEW METHOD FOR CALCULATING 1-PARTICLE GREENS FUNCTION WITH APPLICATION TO ELECTRON-GAS PROBLEM [J].

HEDIN, L .

PHYSICAL REVIEW, 1965, 139 (3A) :A796-+

[6] AB-INITIO MOLECULAR-DYNAMICS SIMULATION OF THE LIQUID-METAL AMORPHOUS-SEMICONDUCTOR TRANSITION IN GERMANIUM [J].

KRESSE, G ;

HAFNER, J .

PHYSICAL REVIEW B, 1994, 49 (20) :14251-14269

[7] ABINITIO MOLECULAR-DYNAMICS FOR LIQUID-METALS [J].

KRESSE, G ;

HAFNER, J .

PHYSICAL REVIEW B, 1993, 47 (01) :558-561

[8] Two-Dimensional Materials from Data Filtering and Ab Initio Calculations [J].

Lebegue, S. ;

Bjorkman, T. ;

Klintenberg, M. ;

Nieminen, R. M. ;

Eriksson, O. .

PHYSICAL REVIEW X, 2013, 3 (03) :1-7

[9] Implementation of an all-electron GW approximation based on the projector augmented wave method without plasmon pole approximation:: Application to Si, SiC, AlAs, InAs, NaH, and KH -: art. no. 155208 [J].

Lebègue, S ;

Arnaud, B ;

Alouani, M ;

Bloechl, PE .

PHYSICAL REVIEW B, 2003, 67 (15)

[10] Novel in situ template-controlled route to CuS nanorods via transition metal liquid crystals [J].

Lu, J ;

Zhao, Y ;

Chen, N ;

Xie, Y .

CHEMISTRY LETTERS, 2003, 32 (01) :30-31

← 1 2 3 →