Asymmetric synthesis of cyclopropanes from lithiated aryloxiranes and α,β-unsaturated Fischer carbene complexes

被引：31

作者：

Capriati, V

Florio, S

Luisi, R

Perna, FM

Barluenga, J

机构：

[1] Univ Bari, Dipartimento Farmaco Chim, I-70126 Bari, Italy

[2] Univ Oviedo, CSIC, Inst Univ Quim Organometal Enrique Moles, E-33006 Oviedo, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 15期

关键词：

D O I：

10.1021/jo050443r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A diastereo- and enantiospecific formation of tetrasubstituted cyclopropane carbene complexes and cyclopropanecarboxylates from lithiated aryloxiranes and alpha,beta-unsaturated Fischer carbene complexes is described.

引用

页码：5852 / 5858

页数：7

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