Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks

被引：55

作者：

Burrows, Andrew D. ^{[1
]}

Fisher, Laura C. ^{[1
,2
]}

Richardson, Christopher ^{[1
,3
]}

Rigby, Sean P. ^{[2
,4
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Univ Bath, Dept Chem Engn, Bath BA2 7AY, Avon, England

[3] Univ Wollongong, Sch Chem, Wollongong, NSW 2522, Australia

[4] Univ Nottingham, Dept Chem & Environm Engn, Nottingham NG7 2RD, England

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

POROUS MATERIALS; MOFS; CRYSTALS; STORAGE; DESIGN;

D O I：

10.1039/c1cc10143a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc(II) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H(2)bdc) and 2-halo-1,4-benzenedicarboxylic acid (H(2)bdc-X, X = Br or I) to give [Zn(4)O(bdc)(3-x)(bdc-X)(x)], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time.

引用

收藏

页码：3380 / 3382

页数：3

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