Composition and structure of enriched alloy layers in filmed Al alloys studied by medium-energy ion scattering

被引:19
作者
Bailey, P [1 ]
Skeldon, P
Noakes, TCQ
Thompson, GE
Sakairi, M
Habazaki, H
Shimizu, K
机构
[1] CLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England
[2] Univ Manchester, Inst Sci & Technol, Ctr Corros & Protect, Manchester M60 1QD, Lancs, England
[3] Hokkaido Univ, Grad Sch Engn, Kita Ku, Sapporo, Hokkaido 0608628, Japan
[4] Keio Univ, Univ Chem Lab, Yokohama, Kanagawa 223, Japan
关键词
aluminium; alloys; copper; depth profiling; MEIS;
D O I
10.1002/sia.1098
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The topmost 20 nm of an electropolished Al-1 at.% Cu alloy has been investigated at sub-nanometre resolution using medium-energy ion scattering. Differences in the composition and depth of the enriched Cu layer are observed. Most significantly, the enriched layer contains regions of differing structure and/or lattice orientation with Cu atoms located in distinct ordered regions, consist ent with the presence of Cu-rich clusters, Surface-segregated Si and Cu are observed and CI and Cu are found in the oxide. Copyright (C) 2001 John Wiley & Sons, Ltd.
引用
收藏
页码:480 / 483
页数:6
相关论文
共 19 条
[1]   A medium energy ion scattering study of the structure of Sb overlayers on Cu(111) [J].
Bailey, P ;
Noakes, TCQ ;
Woodruff, DP .
SURFACE SCIENCE, 1999, 426 (03) :358-372
[2]   Structure determination of the Cu(100)c(2x2)-Mn and Cu(100)c(2x2)-Au surface alloy phases by medium-energy ion scattering [J].
Brown, D ;
Noakes, TCQ ;
Woodruff, DP ;
Bailey, P ;
Le Goaziou, Y .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1999, 11 (08) :1889-1901
[3]   ELASTIC RECOIL DETECTION FOR MEDIUM-ENERGY ION-SCATTERING [J].
COPEL, M ;
TROMP, RM .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1993, 64 (11) :3147-3152
[4]   Cu segregation at the Al(Cu)Al2O3 interface [J].
Copel, M ;
Rodbell, KP ;
Tromp, RM .
APPLIED PHYSICS LETTERS, 1996, 68 (12) :1625-1627
[5]   The importance of surface treatment to the anodic oxidation behaviour of Al-Cu alloys [J].
Habazaki, H ;
Paez, MA ;
Shimizu, K ;
Skeldon, P ;
Thompson, GE ;
Wood, GC ;
Zhou, X .
CORROSION SCIENCE, 1996, 38 (07) :1033-1042
[6]   Effects of alloying elements in anodizing of aluminium [J].
Habazaki, H ;
Shimizu, K ;
Skeldon, P ;
Thompson, GE ;
Wood, GC ;
Zhou, X .
TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING, 1997, 75 :18-23
[7]   Nanoscale enrichments of substrate elements in the growth of thin oxide films [J].
Habazaki, H ;
Shimizu, K ;
Skeldon, P ;
Thompson, GE ;
Wood, GC ;
Zhou, X .
CORROSION SCIENCE, 1997, 39 (04) :731-737
[8]   The incorporation of metal ions into anodic films on aluminium alloys [J].
Habazaki, H ;
Shimizu, K ;
Skeldon, P ;
Thompson, GE ;
Wood, GC .
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1996, 73 (03) :445-460
[9]  
JEYNES C, WINDF DATA FURNANCE
[10]  
MORISAKI S, 1998, J SURF FINISH SOC JP, V49, P205