Radical addition reactions of chiral phosphorus hydrides

被引：26

作者：

Jessop, CM

Parsons, AF ^{[1
]}

Routledge, A

Irvine, DJ

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Uniqema, Wilton Ctr, Redcar TS10 4RF, England

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 19期

基金：

英国生物技术与生命科学研究理事会;

关键词：

D O I：

10.1016/j.tetasy.2003.04.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Intermolecular radical addition of a (1R,2R,3S,5R)-(-)-pinanediol-derived thiophosphite leads to the diastereoselective formation of organophosphorus adducts. Addition of the intermediate phosphonothioyl radical to electron-rich alkenes or alkynes occurs with retention of configuration at phosphorus. (C) 2003 Elsevier Ltd. All rights reserved.

引用

收藏

页码：2849 / 2851

页数：3

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