Enantioselective addition of diethylzinc to benzaldehyde in the presence of sulfur-containing pyridine ligands

被引：31

作者：

Chelucci, G

Berta, D

Fabbri, D

Pinna, GA

Saba, A

Ulgheri, F

机构：

[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

[2] CNR, Ist Applicaz Tecn Chim Avanzate Problemi Agro, I-07100 Sassari, Italy

[3] CNR, Dipartimento Farmaco Tossicol, I-07100 Sassari, Italy

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(98)00167-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diastereomerically pure hydroxy and thiol derivatives of (5S,7S)-5,7-methane-6,6-dimethyl-2-phenyl-5,6,7,8- tetrahydroquinoline were prepared and assessed in the enantioselective addition of diethylzinc to benzaldehyde: enantioselectivities up to 62% were obtained. (C) 1998 Elsevier Science Ltd. AII rights reserved.

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页码：1933 / 1940

页数：8

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