Synthesis, crystal structure and luminescent properties of one new inorganic-organic hybrid compound [O2NBzQL]4[Cd(SCN)4(NCS)2] (O2NBzQL=1-(4′-NO2-benzyl)quinolinium cation)

被引:30
作者
Bai, Yan [1 ]
Hu, Xue-Fu [1 ]
Dang, Dong-Bin [1 ]
Bi, Feng-Lei [1 ]
Niu, Jing-Yang [1 ]
机构
[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475004, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Cadmium(II) complex; Thiocyanato; Crystal structure; Luminescent properties; COORDINATION POLYMERS; MAGNETIC TRANSITION; COMPLEX; THIOCYANATE; CHAIN; LIGANDS; IONS;
D O I
10.1016/j.saa.2010.08.066
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
A new inorganic-organic hybrid compound (O(2)NBzQL](4)[Cd(SCN)(4)(NCS)(2)] (O(2)NBzQL = 1-(4'-NO2-benzyl)quinolinium cation) has been synthesized and characterized by IR, UV, elemental analysis and X-ray crystallography. Cd(II) atom has an distorted octahedral environment with an N4S2 donor set. In solid state there are three types of face-to-face pi-pi interactions between adjacent cations and multiform C-H center dot center dot center dot S and C-H center dot center dot center dot N hydrogen bonds between [O(2)NBzQL](+) cations and cadmium thiocyanate anions. The luminescent properties of the title compound were both investigated in H2O solution and in solid state at room temperature, respectively. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:70 / 73
页数:4
相关论文
共 20 条
[1]   Synthesis, Crystal Structure and Luminescent Properties of One Cadmium(II) Coordination Polymer with Mixed Thiocyanate and Quinoline Ligands [J].
Bai, Yan ;
Gao, Hui ;
Dang, Dong-Bin ;
Hu, Xue-Fu ;
Guo, Xiang-Yang .
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2009, 39 (09) :512-515
[2]   Synthesis, crystal structure and luminescent properties of a thiocyanato bridged two-dimensional heteronuclear polymeric complex of cadmium(II) and copper(II) [J].
Bai, Yan ;
Shang, Wei-Li ;
Dang, Dong-Bin ;
Gao, Hui ;
Niu, Xiao-Fang ;
Guan, Yang-Fan .
INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (12) :1470-1473
[3]   CONFORMATIONAL INVESTIGATION OF N-ARALKYLPYRIDINIUM IONS BY COTTON MOUTON EFFECT METHOD [J].
BULGAREVICH, SB ;
BREN, DV ;
MOVSHOVIC, DY ;
FINOCCHIARO, P ;
FAILLA, S .
JOURNAL OF MOLECULAR STRUCTURE, 1994, 317 (1-2) :147-155
[4]   1D looped chain, 1D tube-like chain, and 3D inorganic-organic hybrid coordination polymers assembled from 1,6-di(triazole-1-yl-methyl)-4-R-phenol and cadmium(II) thiocyanate [J].
Chu, Zhao-Lian ;
Zhu, Hai-Bin ;
Hu, Da-Hua ;
Huang, Wei ;
Gou, Shao-Hua .
CRYSTAL GROWTH & DESIGN, 2008, 8 (05) :1599-1604
[5]   Two versatile N,N′-bipyridine-type ligands for preparing organic-inorganic coordination polymers:: New cobalt- and nickel-containing framework materials [J].
Ciurtin, DM ;
Dong, YB ;
Smith, MD ;
Barclay, T ;
zur Loye, HC .
INORGANIC CHEMISTRY, 2001, 40 (12) :2825-2834
[6]   Peculiar magnetic transition behaviour around 208 K in one-dimensional nickel(III) chain complex [1-(4′-vinylbenzyl)pyridinium][Ni(mnt)2] (mnt2- = maleonitriledithiolate) [J].
Dang, DB ;
Ni, CL ;
Bai, Y ;
Tian, ZF ;
Ni, ZP ;
Wen, LL ;
Meng, QJ ;
Gao, S .
CHEMISTRY LETTERS, 2005, 34 (05) :680-681
[7]   Synthesis, crystal structure and luminescent properties of two cadmium thiocyanate coordination polymers with benzylpyridyl cations [J].
Dang, Dong-Bin ;
Shang, Wei-Li ;
Bai, Yan ;
Sun, Ji-De ;
Gao, Hui .
INORGANICA CHIMICA ACTA, 2009, 362 (07) :2391-2395
[8]   Synthesis, Characterization and Crystal Structure Determination of a Hepta-coordinated Cadmium(II) Complex with Thiocyanatobridges [J].
Dang, Dongbin ;
Sun, Jide ;
Bai, Yan ;
Gao, Hui ;
Shang, Weili .
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2009, 39 (09) :683-687
[9]   EQUILIBRIUM CONSTANTS FOR PYRIDINIUM IODIDE CHARGE-TRANSFER COMPLEX FORMATION [J].
KOSOWER, EM ;
BURBACH, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (22) :5838-5842
[10]   PYRIDINIUM COMPLEXES .1. THE SIGNIFICANCE OF THE 2ND CHARGE-TRANSFER BAND OF PYRIDINIUM IODIDES [J].
KOSOWER, EM ;
SKORCZ, JA ;
SCHWARZ, WM ;
PATTON, JW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (09) :2188-2191