An aluminum complex supported by a fluorous diamino-dialkoxide ligand for the highly productive ring-opening polymerization of ε-caprolactone

被引：74

作者：

Amgoune, A

Lavanant, L

Thomas, CM

Chi, Y

Welter, R

Dagorne, S ^{[1
]}

Carpentier, JF

机构：

[1] Univ Rennes 1, Inst Chim Rennes, CNRS, UMR 6509,, F-35042 Rennes, France

[2] Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan

[3] Univ Louis Pasteur Strasbourg 1, Inst Le Bel, Lab DECMET, F-67000 Strasbourg, France

[4] Ecole Natl Super Chim Paris, CNRS, UMR 7576, Lab Chim Organomet, F-75231 Paris, France

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 25期

关键词：

D O I：

10.1021/om050512s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new discrete aluminum alkoxide complex (iPrO)Al{CH2NMeCH2C(CF3)(2)O}(2) (1) initiates the controlled ring-opening polymerization of caprolactone in dichloromethane at 20 degrees C with high activity (TOF = 250 h(-1)) and productivity (TON up to 1000), leading to polymers with high molecular weight and narrow molecular weight distribution.

引用

收藏

页码：6279 / 6282

页数：4

相关论文

共 17 条

[1]

ALCAZARROMAN LM, 2003, J CHEM SOC DA, P3082

[2] Aluminum complexes supported by tridentate aminophenoxide ligand as efficient catalysts for ring-opening polymerization of ε-caprolactone [J].

Chen, CT ;

Huang, CA ;

Huang, BH .

MACROMOLECULES, 2004, 37 (21) :7968-7973

[3]

CHEN CT, 2003, J CHEM SOC DA, P3799

[4] Fluorinated aminoalkoxide CuII complexes:: new CVD precursors for deposition of copper metal [J].

Chi, Y ;

Hsu, PF ;

Liu, CS ;

Ching, WL ;

Chou, TY ;

Carty, AJ ;

Peng, SM ;

Lee, GH ;

Chuang, SH .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (12) :3541-3550

[5] Controlled ring-opening polymerization of lactide and glycolide [J].

Dechy-Cabaret, O ;

Martin-Vaca, B ;

Bourissou, D .

CHEMICAL REVIEWS, 2004, 104 (12) :6147-6176

[6] Salt-free synthesis of samarium-aluminum mixed-metal alkoxides:: X-ray crystal structures of {[(i-Pr-O)(i-Bu)Al(μ-O-i-Pr)2Sm(O-i-Pr)(HO-i-Pr)](μ-O-i-Pr)}2, [(THF)2Sm(O-t-Bu)2(μ-O-t-Bu)2Al(i-Bu)2], Sm(OAr)3(THF)3 (Ar=2,4,6-Me3C6H2), [Nd(μ-OAr)(OAr)2(py)2]2 (Ar=2,4,6-Me3C6H2), and (ArO)3Sm[(μ-O-t-Bu)2Al2(O-t-Bu)4] (Ar=2,6-i-Pr2C6H3) [J].

Giesbrecht, GR ;

Gordon, JC ;

Clark, DL ;

Scott, BL ;

Watkin, JG ;

Young, KJ .

INORGANIC CHEMISTRY, 2002, 41 (24) :6372-6379

[7] Remarkable stereocontrol in the polymerization of racemic lactide using aluminum initiators supported by tetradentate aminophenoxide ligands [J].

Hormnirun, P ;

Marshall, EL ;

Gibson, VC ;

White, AJP ;

Williams, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (09) :2688-2689

[8] C2-symmetiric fluorous diamino-dialkoxide complexes of early transition metals [J].

Lavanant, L ;

Chou, TY ;

Chi, Y ;

Yun, C ;

Lehmann, CW ;

Toupet, L ;

Carpentier, JF .

ORGANOMETALLICS, 2004, 23 (23) :5450-5458

[9] Alcoholysis of methyl aluminium biphenoxides:: Excellent initiators for the ring opening polymerisation of ε-caprolactone [J].

Liao, TC ;

Huang, YL ;

Huang, BH ;

Lin, CC .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2003, 204 (5-6) :885-892

[10] A highly efficient catalyst for the "living" and "immortal" polymerization of ε-caprolactone and L-lactide [J].

Liu, YC ;

Ko, BT ;

Lin, CC .

MACROMOLECULES, 2001, 34 (18) :6196-6201