Toward the Self-Assembly of Metal-Organic Nanotubes Using Metal-Metal and π-Stacking Interactions: Bis(pyridylethynyl) Silver(I) Metallo-macrocycles and Coordination Polymers

被引：66

作者：

Kilpin, Kelly J. ^{[1
]}

Gower, Martin L. ^{[1
]}

Telfer, Shane G. ^{[2
,3
]}

Jameson, Geoffrey B. ^{[2
]}

Crowley, James D. ^{[1
]}

机构：

[1] Univ Otago, Dept Chem, Dunedin, New Zealand

[2] Massey Univ, Inst Fundamental Sci, Palmerston North, New Zealand

[3] MacDiarmid Inst Adv Mat & Nanotechnol, Wellington, New Zealand

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 03期

关键词：

MAGNUS GREEN SALT; SHAPE-PERSISTENT MACROCYCLES; RAY CRYSTAL-STRUCTURE; HOST-GUEST FORMATION; CENTER-DOT-PT; SUPRAMOLECULAR CHEMISTRY; MOLECULAR RECOGNITION; METALLOSUPRAMOLECULAR ASSEMBLIES; GOLD NANOPARTICLES; LIQUID-CRYSTALS;

D O I：

10.1021/ic1020059

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Shape-persistent macrocycles and planar organometallic complexes are beginning to show considerable promise as building blocks for the self-assembly of a variety of supramolecular materials including nanofibers, nanowires, and liquid crystals. Here we report the synthesis and characterization of a family of planar di- and tri-silver(I) containing metallo-macrocycles designed to self-assemble into novel metal-organic nanotubes through a combination of pi-stacking and metal-metal interactions. The silver(I) complexes have been fully characterized by elemental analysis, high resolution electrospray ionization mass spectrometry (HR-ESI-MS), IR, H-1 and C-13 NMR spectroscopy, and the solution data are consistent with the formation of the metallo-macrocycles. Four of the complexes have been structurally characterized using X-ray crystallography. However, only the di-silver(I) complex formed with 1,3-bis(pyridin-3-ylethynyl)benzene is found to maintain its macrocyclic structure in the solid state. The di-silver(I) shape. persistent macrocycle assembles into a nanoporous chicken-wire like structure, and CIO4- anions and disordered H2O molecules fill the pores. The silver(I) complexes of 2,6-bis(pyridin-3-ylethynyl)pyridine and 1,4-di(3-pyridyl)buta-1,3-diyne ring-open and crystallize as non-porous coordination polymers.

引用

页码：1123 / 1134

页数：12

共 168 条

[1] Variable Ag(I) coordination modes in silver cobalt(III) bis(dicarbollide) supramolecular assemblies with cyclotriveratrylene host molecules [J].