Visible light induced reversible extrusion of nitric oxide from a ruthenium(II) nitrosyl complex: A facile delivery of nitric oxide

被引：35

作者：

Prakash, R ^{[1
]}

Czaja, AU ^{[1
]}

Heinemann, FW ^{[1
]}

Sellmann, D ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Anorgan Chem, D-91058 Erlangen, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 40期

关键词：

D O I：

10.1021/ja053758x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new ruthenium compound [Ru(NO)(pysiS4)]Br (3) (pysiS4 = 2,6-bis(3-triphenylsilyl-2-sulfanylphenylthiomethyl)pyridine), containing sterically bulky SiPh3 groups ortho to the thiolate donors, has been synthesized. In solution, 3 releases NO efficiently on exposure to visible light (λ ≥ 455 nm) at room temperature to afford [Ru(Br)(pysiS4)] (4). Treatment of 4 with NO yielded exclusively 3 without any metal-bound side reaction. Copyright © 2005 American Chemical Society.

引用

页码：13758 / 13759

页数：2

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