Oxocluster-reinforced organic-inorganic hybrid materials: effect of transition metal oxoclusters on structural and functional properties

被引:49
作者
Gross, Silvia [1 ,2 ]
机构
[1] Univ Padua, Dipartimento Sci Chim, ISTM CNR, I-35131 Padua, Italy
[2] INSTM UdR Padova, I-35131 Padua, Italy
关键词
NANOSIZED BUILDING-BLOCKS; OXIDES MO2-SIO2 M; SOLID-STATE NMR; MOLECULAR-STRUCTURE; NANOBUILDING BLOCKS; THERMAL-STABILITY; CRYSTAL-STRUCTURE; OXO CLUSTERS; POLY(METHYL METHACRYLATE); SUBSTITUTED OXOTITANIUM;
D O I
10.1039/c1jm10579e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The focus of this Highlight is on the structural and functional properties which organically modified transition oxoclusters can provide, once embedded into a polymer matrix, to the resulting hybrid materials. Some selected case studies are discussed to highlight the role of these polynuclear inorganic building blocks in determining appealing material properties.
引用
收藏
页码:15853 / 15861
页数:9
相关论文
共 154 条
[81]   Spin qubits with electrically gated polyoxometalate molecules [J].
Lehmann, Joerg ;
Gaita-Arino, Alejandro ;
Coronado, Eugenio ;
Loss, Daniel .
NATURE NANOTECHNOLOGY, 2007, 2 (05) :312-317
[82]   Polyhedral oligomeric silsesquioxane (POSS) polymers and copolymers: A review [J].
Li, GZ ;
Wang, LC ;
Ni, HL ;
Pittman, CU .
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2001, 11 (03) :123-154
[83]   Fully condensed polyhedral oligosilsesquioxanes(POSS): From synthesis to application [J].
Lickiss, Paul D. ;
Rataboul, Franck .
ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 57, 2008, 57 :1-116
[84]  
Lira-Cantu M, 1997, RRD PHYS CHEM, V1, P379
[85]  
LIU J, 2007, REC PAT ENG, V1, P214
[86]   Linking chiral clusters with molybdate building blocks:: From homochiral helical supramolecular arrays to coordination helices [J].
Long, De-Liang ;
Koegerler, Paul ;
Farrugia, Louis J. ;
Cronin, Leroy .
CHEMISTRY-AN ASIAN JOURNAL, 2006, 1 (03) :352-357
[87]   Synthesis, characterization and electrochemical properties of trinuclear iron(III) complexes containing unsaturated carboxylate bridging ligands [J].
Losada, G ;
Mendiola, MA ;
Sevilla, MT .
INORGANICA CHIMICA ACTA, 1997, 255 (01) :125-131
[88]   Heterometal expansion of oxozirconium carboxylate clusters [J].
Malaestean, Iurii L. ;
Speldrich, Manfred ;
Ellern, Arkady ;
Baca, Svetlana G. ;
Koegerler, Paul .
DALTON TRANSACTIONS, 2011, 40 (02) :331-333
[89]   Mechanical properties of hybrid organic-inorganic materials [J].
Mammeri, F ;
Le Bourhis, E ;
Rozes, L ;
Sanchez, C .
JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (35-36) :3787-3811
[90]  
MATYJASZEWSKI K, 2003, QUANTUM OPT, V30, P167