Heterometal expansion of oxozirconium carboxylate clusters

被引:34
作者
Malaestean, Iurii L. [1 ]
Speldrich, Manfred [1 ]
Ellern, Arkady [2 ]
Baca, Svetlana G. [3 ]
Koegerler, Paul [1 ,2 ]
机构
[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52074 Aachen, Germany
[2] Iowa State Univ, Ames Lab, Ames, IA 50011 USA
[3] ASM, Inst Chem, Kishinev 2028, Moldova
关键词
MOLECULAR SPINTRONICS; BUILDING-BLOCKS; SYSTEMS; ZR6O4(OH)(4)(OOCR)(12); MAGNETS; CORE;
D O I
10.1039/c0dt01136c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Although representing a 'thermodynamic sink', the octahedral oxozirconium {Zr6O4(OH)(4)} cluster structure can be magnetically functionalized by up to six 3d metal cations with a combination of flexible aminoalkoxide and carboxylate ligands.
引用
收藏
页码:331 / 333
页数:3
相关论文
共 23 条
[1]   Molecular spintronics using single-molecule magnets [J].
Bogani, Lapo ;
Wernsdorfer, Wolfgang .
NATURE MATERIALS, 2008, 7 (03) :179-186
[2]   A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].
Cavka, Jasmina Hafizovic ;
Jakobsen, Soren ;
Olsbye, Unni ;
Guillou, Nathalie ;
Lamberti, Carlo ;
Bordiga, Silvia ;
Lillerud, Karl Petter .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851
[3]   Molecular spintronics and quantum computing [J].
Coronado, Eugenio ;
Epsetin, Arthur J. .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (12) :1670-1671
[4]   A polyoxometalate-based manganese carboxylate cluster [J].
Fang, Xikui ;
Koegerler, Paul .
CHEMICAL COMMUNICATIONS, 2008, (29) :3396-3398
[5]   Stereoisomerism in polyoxometalates: structural and spectroscopic studies of bis(malate)-functionalized cluster systems [J].
Fang, XK ;
Anderson, TM ;
Hou, Y ;
Hill, CL .
CHEMICAL COMMUNICATIONS, 2005, (40) :5044-5046
[6]   Enantiomerically pure polytungstates: Chirality transfer through zirconium coordination centers to nanosized inorganic clusters [J].
Fang, XK ;
Anderson, TM ;
Hill, CL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (23) :3540-3544
[7]   A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates [J].
Guillerm, Vincent ;
Gross, Silvia ;
Serre, Christian ;
Devic, Thomas ;
Bauer, Matthias ;
Ferey, Gerard .
CHEMICAL COMMUNICATIONS, 2010, 46 (05) :767-769
[8]   Polyoxometalates: Introduction to a class of inorganic compounds and their biomedical applications [J].
Hasenknopf, B .
FRONTIERS IN BIOSCIENCE-LANDMARK, 2005, 10 :275-287
[9]   Special issue: Polyoxometalates in catalysis - Foreword [J].
Hill, Craig L. .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 262 (1-2) :1-1
[10]   Variations in capping the Zr6O4(OH)4 cluster core.: X-ray structure analyses of [Zr6(OH)4O4(OOC-CH=CH2)10]2(μ-OOC-CH=CH2)4 and Zr6(OH)4O4(OOCR)12(PrOH) (R = Ph, CMe = CH2) [J].
Kickelbick, G ;
Wiede, P ;
Schubert, U .
INORGANICA CHIMICA ACTA, 1999, 284 (01) :1-7