One-step growth of ZnO from film to vertically well-aligned nanorods and the morphology-dependent Raman scattering

被引:108
作者
Cong, GW [1 ]
Wei, HY [1 ]
Zhang, PF [1 ]
Peng, WQ [1 ]
Wu, JJ [1 ]
Liu, XL [1 ]
Jiao, CM [1 ]
Hu, WG [1 ]
Zhu, QS [1 ]
Wang, ZG [1 ]
机构
[1] Chinese Acad Sci, Inst Semicond, Key Lab Semicond Mat Sci, Beijing 100083, Peoples R China
关键词
D O I
10.1063/1.2137308
中图分类号
O59 [应用物理学];
学科分类号
摘要
We observed a transition from film to vertically well-aligned nanorods for ZnO grown on sapphire (0001) substrates by metalorganic chemical vapor deposition. A growth mechanism was proposed to explain such a transition. Vertically well-aligned homogeneous nanorods with average diameters of similar to 30, 45, 60, and 70 nm were grown with the c-axis orientation. Raman scattering showed that the E-2 (high) mode shifted to high frequency with the decrease of nanorod diameters, which revealed the dependence of nanorod diameters on the stress state. This dependence suggests a stress-driven diameter-controlled mechanism for ZnO nanorod arrays grown on sapphire (0001) substrates. (c) 2005 American Institute of Physics.
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页码:1 / 3
页数:3
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