Electrical resistivity of graphitized ultra-disperse diamond and onion-like carbon

被引:128
作者
Kuznetsov, VL
Butenko, YV
Chuvilin, AL
Romanenko, AI
Okotrub, AV
机构
[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[2] Inst Inorgan Chem, Novosibirsk 630090, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1016/S0009-2614(01)00135-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Here we present the result of measurements of electrical resistivity of ultra-disperse diamonds (UDD) with different graphitization degrees and onion-like carbon (OLC) prepared by vacuum annealing of UDD samples at various fixed temperatures. Intermediate samples contain particles with a diamond core covered by closed curved graphitic shells. The temperature dependence of electrical resistivity rho (T) of these structures is characteristic for the systems with localized electrons and variable hopping-length hopping conductivity (VHLHC). The data on sample resistance are discussed in terms of the variation of dimensionality of conductivity and changing the number of defects in the system. (C) 2001 Published by Elsevier Science B.V.
引用
收藏
页码:397 / 404
页数:8
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