Heterogeneously catalysed Strecker-type reactions using supported Co(II) catalysts: microwave vs. conventional heating

被引：39

作者：

Rajabi, Fatemeh ^{[1
]}

Nourian, Saghar ^{[2
]}

Ghiassian, Sara ^{[2
]}

Balu, Alina M. ^{[3
]}

Saidi, Mohammad Reza ^{[2
]}

Carlos Serrano-Ruiz, Juan ^{[3
]}

Luque, Rafael ^{[3
]}

机构：

[1] Payame Noor Univ, Dept Sci, Tehran, Iran

[2] Sharif Univ Technol, Dept Chem, Tehran, Iran

[3] Univ Cordoba, Dept Quim Organ, E-14014 Cordoba, Spain

来源：

GREEN CHEMISTRY | 2011年 / 13卷 / 11期

关键词：

ALPHA-AMINO-ACIDS; SOLVENT-FREE SYNTHESIS; ASYMMETRIC-SYNTHESIS; EFFICIENT CATALYST; AEROBIC OXIDATION; HIGHLY EFFICIENT; COBALT COMPLEX; AMINONITRILES; SILICA; KETIMINES;

D O I：

10.1039/c1gc15741h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A range of alpha-aminonitriles could be efficiently prepared from various aldehydes/ketones and primary or secondary amines using a highly active and stable Co(II) complex supported on different mesoporous supports at both room temperature and low temperature microwave irradiation under solventless conditions. Catalysts were also highly reusable under the investigated reaction conditions and could be reused at least 10 times without loss of catalytic activity.

引用

收藏

页码：3282 / 3289

页数：8

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