Towards a methanol economy based on homogeneous catalysis: methanol to H2 and CO2 to methanol

被引：170

作者：

Alberico, E. ^{[1
,2
]}

Nielsen, M. ^{[3
,4
]}

机构：

[1] CNR, Ist Chim Biomol, I-07100 Sassari, Italy

[2] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany

[3] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

[4] Tech Univ Denmark, Dept Chem, Ctr Catalysis & Sustainable Chem, DK-2800 Lyngby, Denmark

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 31期

关键词：

LIQUID-PHASE DEHYDROGENATION; METAL-LIGAND COOPERATION; METHYL ACETATE FORMATION; CARBON-DIOXIDE; HYDROGEN-PRODUCTION; FORMIC-ACID; PHOTOCATALYTIC DEHYDROGENATION; BOND ACTIVATION; ACETIC-ACID; EFFICIENT;

D O I：

10.1039/c4cc09471a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The possibility to implement both the exhaustive dehydrogenation of aqueous methanol to hydrogen and CO2 and the reverse reaction, the hydrogenation of CO2 to methanol and water, may pave the way to a methanol based economy as part of a promising renewable energy system. Recently, homogeneous catalytic systems have been reported which are able to promote either one or the other of the two reactions under mild conditions. Here, we review and discuss these developments.

引用

页码：6714 / 6725

页数：12

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