Ligand substitution reactions at inorganic centers

被引：294

作者：

Richens, DT ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMICAL REVIEWS | 2005年 / 105卷 / 06期

关键词：

D O I：

10.1021/cr030705u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review on ligand substitution reactions at inorganic centers focuses on nonsymmetrical substitution processes dealing with complex-formation reactions. The role of solvent exchange reactions is reviewed followed by a systematic survey of ligand substitution reactions on four, five-, six-, seven-, eight-, and nine-coordinate metal centers. The influence of labilization effects caused by hydroxyl ligands, metal-carbon bonds, terminal and bridged oxo and nitride ligands, and the behavior of polynuclear clusters is also highlighted.

引用

页码：1961 / 2002

页数：42

共 340 条

[1] THE RELATIVE NUCLEOPHILIC EFFICIENCY OF WATER AND DIMETHYLSULFOXIDE IN THE AQUEOUS SUBSTITUTION OF AQUAPENTACYANOCOBALTATE(III) AND CHLOROPENTACYANOCOBALTATE(III)
ABOUELWAFA, MHM
BURNETT, MG
MCCULLAGH, JF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (10): : 2311 - 2316
[2] THE DISSOCIATIVE INTERCHANGE SUBSTITUTION OF THE PENTACYANOCOBALTATE(III) SERIES OF COMPLEXES, (CO(CN)5X)2-,(CO(CN)5X)3-
ABOUELWAFE, MHM
BURNETT, MG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (15) : 833 - 834
[3] PROTON-EXCHANGE AND BASE HYDROLYSIS OF BETA-CIS-DICHLORO(1,9-DIAMINO-3,7-DIAZANONANE)COBALT(III) CATIONS
AHMED, E
TOBE, ML
[J]. INORGANIC CHEMISTRY, 1976, 15 (11) : 2635 - 2639
[4] THE RELATIVE AFFINITIES OF LIGAND ATOMS FOR ACCEPTOR MOLECULES AND IONS
AHRLAND, S
CHATT, J
DAVIES, NR
[J]. QUARTERLY REVIEWS, 1958, 12 (03): : 265 - 276
[5] Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes
Aime, S
Barge, A
Batsanov, AS
Botta, M
Delli Castelli, D
Fedeli, F
Mortillaro, A
Parker, D
Puschmann, H
[J]. CHEMICAL COMMUNICATIONS, 2002, (10) : 1120 - 1121
[6] NMR, relaxometric, and structural studies of the hydration and exchange dynamics of cationic lanthanide complexes of macrocyclic tetraamide ligands
Aime, S
Barge, A
Bruce, JI
Botta, M
Howard, JAK
Moloney, JM
Parker, D
de Sousa, AS
Woods, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (24) : 5762 - 5771
[7] Prototropic and water-exchange processes in aqueous solutions of Gd(III) chelates
Aime, S
Botta, M
Fasano, M
Terreno, E
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) : 941 - 949
[8] CUBANE-TYPE MOLYBDENUM AQUA IONS - PREPARATION AND STRUCTURES OF [MO4(MU-3-O)(MU-3-S)3(H2O)12]5+ AND [MO4(MU-3-S)4(H2O)12]5+
AKASHI, H
SHIBAHARA, T
NARAHARA, T
TSURU, H
KUROYA, H
[J]. CHEMISTRY LETTERS, 1989, (01) : 129 - 132
[9] Alberto R, 1999, COORDIN CHEM REV, V190, P901
[10] ELECTRONIC AND STERIC EFFECTS IN THE DISSOCIATIVE DISPLACEMENT OF THIOETHERS FROM MIXED PHENYL(THIOETHER)PLATINUM(II) COMPLEXES
ALIBRANDI, G
MINNITI, D
SCOLARO, LM
ROMEO, R
[J]. INORGANIC CHEMISTRY, 1989, 28 (10) : 1939 - 1943

← 1 2 3 4 5 6 7 8 9 10 →