Iron complexes of the N(CH2CH2S)33-(NS3) ligand with isocyanide co-ligands.

被引：3

作者：

Cooper, L

Davies, SC

Dilworth, JR

Hughes, DL

Konkol, M

Richards, RL

Sanders, JR

Sobota, P

机构：

[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

[2] John Innes Ctr Plant Sci Res, Dept Biol Chem, Norwich NR4 7UH, Norfolk, England

[3] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2001年 / 79卷 / 5-6期

关键词：

iron; cobalt; nickel; thiolate; isocyanide;

D O I：

10.1139/cjc-79-5-6-490

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes NEt4[Fe(NS3)(CNR)] (1), [Fe{Fe(NS3)(CNR)}(2)-S,S'] (2), [Co{Fe(NS3)(CNMe)}(2)-S,S' ] (3), and [Ni{Fe(NS3)(CNMe)}(2)-S,S'] (4) (R = Me, t-Bu, or C6H11(Cy)) have been prepared and the X-ray crystal structures of NEt4[Fe(NS3)(CNMe)] (1a) and [Fe{Fe(NS3)(CNCy)}(2)-S,S'] (2c) have been determined. Mossbauer and IR spectroscopic data and room temperature magnetic moments for these complexes are reported.

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页码：490 / 494

页数：5

相关论文

共 17 条

[1] DINITROGEN COMPLEXES OF TUNGSTEN WITH BULKY PHOSPHINE CO-LIGANDS - PREPARATION AND CRYSTAL-STRUCTURES OF [(W(N2)2(PET2PH)3)2(MU-N2)], TRANS-[W(N2)2(PET2PH)4].C4H8O, AND "[W(ETA-6-C6H5PPRN2)(N-2)(PPRN2PH)2] AND THEIR REACTIONS TO GIVE HYDRAZINE OR AMMONIA [J].

ANDERSON, SN ;

RICHARDS, RL ;

HUGHES, DL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (02) :245-252

[2]

[Anonymous], 1992, INT TABLES XRAY CRYS, VC, p[500, 219, 193]

[3] DIOXOMOLYBDENUM(VI) COMPLEXES STABILIZED BY POLYDENTATE LIGANDS WITH NO3, N2O2, AND NS2 DONOR-ATOM SETS [J].

BARBARO, P ;

BIANCHINI, C ;

SCAPACCI, G ;

MASI, D ;

ZANELLO, P .

INORGANIC CHEMISTRY, 1994, 33 (14) :3180-3186

[4] Vanadium complexes of the N(CH2CH2S)(3)(3-)-ligand with co-ligands relevant to nitrogen fixation processes [J].

Davies, SC ;

Hughes, DL ;

Janas, Z ;

Jerzykiewicz, L ;

Richards, RL ;

Sanders, JR ;

Sobota, P .

CHEMICAL COMMUNICATIONS, 1997, (14) :1261-1262

[5] Molybdenum and tungsten complexes of the N(CH2CH2S)33- (NS3) ligand with oxide, sulfide, diazenide, hydrazide and nitrosyl co-ligands [J].

Davies, SC ;

Hughes, DL ;

Richards, RL ;

Sanders, JR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (05) :719-725

[6] Synthesis and structure of a thiolate-bridged nickel-iron complex: towards a mimic of the active site of NiFe-hydrogenase [J].

Davies, SC ;

Evans, DJ ;

Hughes, DL ;

Longhurst, S ;

Sanders, JR .

CHEMICAL COMMUNICATIONS, 1999, (19) :1935-1936

[7] Iron complexes of the N(CH2CH2S)33- ligand;: a paramagnetic, trigonal bipyramidal Fe(II) CO complex as a chelate ligand [J].

Davies, SC ;

Hughes, DL ;

Richards, RL ;

Sanders, JR .

CHEMICAL COMMUNICATIONS, 1998, (24) :2699-2700

[8] Vanadium complexes of the N(CH2CH2S)33- and O(CH2CH2S)22- ligands with coligands relevant to nitrogen fixation processes [J].

Davies, SC ;

Hughes, DL ;

Janas, Z ;

Jerzykiewicz, LB ;

Richards, RL ;

Sanders, JR ;

Silverston, JE ;

Sobota, P .

INORGANIC CHEMISTRY, 2000, 39 (16) :3485-3498

[9] TETRATHIOVANADATE(V) AND TETRATHIORHENATE(VII) - STRUCTURES AND REACTIONS, INCLUDING CHARACTERIZATION OF THE VFE2S4 CORE UNIT [J].

DO, YK ;

SIMHON, ED ;

HOLM, RH .

INORGANIC CHEMISTRY, 1985, 24 (26) :4635-4642

[10] FORMATION OF A RHENIUM(III) CARBONYL COMPLEX BY ELECTROPHILIC ATTACK ON RHENIUM ISOCYANIDES - SYNTHESIS AND MOLECULAR-STRUCTURE OF (RE[N(CH2CH2S)(3)][CNC(CH3)(3)]) AND (RE[N(CH2CH2S)(3)](CO)) [J].

GLASER, M ;

SPIES, H ;

LUGGER, T ;

HAHN, FE .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 503 (01) :C32-C35