High-quality epitaxial. LaAlO3 thin films have been obtained on SrTiO3 (100) substrates by metal-organic chemical vapor deposition(MOCVD) adopting an in-situ strategy which uses a Liquid single source consisting of the second-generation La(hfa)(3).diglyme (Hhfa = 1,1,1,5,5,5-hexafluoro-2,4-pentanedione, diglyme = bis(2-methoxyethyl)ether) precursor and Al(acac)(3) (Hacac = acetylacetone). The LaAlO3 films, 400 nm thick, are strongly c-axis oriented with a similar to 0.4 degrees fwhm of the rocking curve [(200) reflection]. Pole figures provide indication of good in-plane texture.