Block copolymers under periodic, strong three-dimensional confinement

被引：129

作者：

Arsenault, AC ^{[1
]}

Rider, DA ^{[1
]}

Tétreault, N ^{[1
]}

Chen, JIL ^{[1
]}

Coombs, N ^{[1
]}

Ozin, GA ^{[1
]}

Manners, I ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 28期

关键词：

D O I：

10.1021/ja052483i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this communication we study the influence of strong 3D confinement on the self-assembly of diblock copolymers containing a polyferrocenylsilane metallopolymer segment. Both silica colloidal crystals and silica inverse colloidal crystals, having nanometer-scale interconnected pore networks, are used as molds to direct the self-assembly. Unusual morphologies, such as concentric shells and branched lamellae, result from the interaction of the polymer with the high surface area topologically periodic templates. Copyright © 2005 American Chemical Society.

引用

页码：9954 / 9955

页数：2

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