Review of metal 1-azaallyl complexes

被引：54

作者：

Caro, CF ^{[1
]}

Lappert, MF ^{[1
]}

Merle, PG ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2001年 / 219卷

基金：

英国工程与自然科学研究理事会;

关键词：

metal 1-azaallyl complexes; bonding modes; four-membered metalloacycles;

D O I：

10.1016/S0010-8545(01)00361-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review provides a comprehensive survey relating to the synthesis, characterisation and reactivity of main group and d- and f-block metal 1-azaallyl complexes. Section 1 introduces the topic and defines the scope of the article, Section 2 considers general methods of preparation and Section 3 discusses the diversity of bonding modes of the 1-azaallylmetal complexes. Section 4 provides a group by group account of metal 1-azaallyls. Section 5 describes in outline the chemistry of related complexes, namely 2-pyridylalkylmetal and related metal complexes. Finally, we provide a table summarising data on individual metal 1-azaallyls. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：605 / 663

页数：59

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