Thin film microfabrication of gold microelectrodes functionalized with thiacalix[4]arene layer: applications to copper ion sensor

被引：24

作者：

Ben Ali, M

Lemiti, M

Jaffrezic-Renault, N

Martelet, C

Chovelon, JM

Ben Ouada, H

机构：

[1] Ecole Cent Lyon, CNRS, UMRS 5621, F-69131 Ecully, France

[2] Fac Sci Monastir, Lab Phys Interfaces, Monastir 5000, Tunisia

[3] INSA Lyon, Phys Mat Lab, Lyon, France

[4] UCB, Lab Applicat Chim Environm, Lyon, France

来源：

THIN SOLID FILMS | 2001年 / 383卷 / 1-2期

关键词：

thin film; microsensor; gold microelectrodes; thiacalix[4]arene; silanization;

D O I：

10.1016/S0040-6090(00)01571-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Thin-film technology of the microelectrode was done using selected protective photoresist combined with chemical/plasma etching. In order to functionalize the prepared gold microelectrodes, a thin thiacalix[4]arene film was deposited using a thermal evaporation technique in a vacuum. The thiacalix[4]arene/microelectrodes have shown good sensitivity and a low detection limit (approx. 10(-7) M) for Cu(II) ions. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：292 / 295

页数：4

相关论文

共 11 条

[1] Thiacalixarenes:: Synthesis and structural analysis of thiacalix[4]arene and of p-tert-butylthiacalix[4]arene [J].

Akdas, H ;

Bringel, L ;

Graf, E ;

Hosseini, MW ;

Mislin, G ;

Pansanel, J ;

De Cian, A ;

Fischer, J .

TETRAHEDRON LETTERS, 1998, 39 (16) :2311-2314

[2] Impedimetric measurements on polarized functionalized platinum electrodes: application to direct immunosensing [J].

Ameur, S ;

Maupas, H ;

Martelet, C ;

Jaffrezic-Renault, N ;

Ben Ouada, H ;

Cosnier, S ;

Labbe, P .

MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC MATERIALS SENSORS AND SYSTEMS, 1997, 5 (02) :111-119

[3] Cyclodextrin-polymethylhydrosiloxane gel as sensitive membrane for heavy ion sensors [J].

Ben Ali, M ;

Kalfat, R ;

Sfihi, H ;

Ben Ouada, H ;

Chovelon, JM ;

Jaffrezic-Renault, N .

MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 1998, 6 (01) :53-58

[4] Silanization of stainless steel surfaces: Influence of application parameters [J].

Chovelon, JM ;

Aarch, LE ;

Charbonnier, M ;

Romand, M .

JOURNAL OF ADHESION, 1995, 50 (01) :43-58

[5] QUANTITATIVE STUDY OF THE HYDROXYLATION AND OF THE CHEMICAL GRAFTING OF OXIDIZED POROUS SILICON [J].

DUVAULTHERRERA, Y ;

JAFFREZICRENAULT, N ;

CLECHET, P ;

SERPINET, J ;

MOREL, D .

COLLOIDS AND SURFACES, 1990, 50 :197-206

[6] High complexation ability of thiacalixarene with transition metal ions. The effects of replacing methylene bridges of tetra(p-t-butyl)calix[4]arenetetrol by epithio groups [J].

Iki, N ;

Morohashi, N ;

Narumi, F ;

Miyano, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (07) :1597-1603

[7] Facile synthesis of p-tert-butylthiacalix[4]arene by the reaction of p-tert-butylphenol with elemental sulfur in the presence of a base [J].

Kumagai, H ;

Hasegawa, M ;

Miyanari, S ;

Sugawa, Y ;

Sato, Y ;

Hori, T ;

Ueda, S ;

Kamiyama, H ;

Miyano, S .

TETRAHEDRON LETTERS, 1997, 38 (22) :3971-3972

[8] UNUSUAL HOST-GUEST PI-ARENE ... H-BONDING IN A HOODED CAVITAND - THE FIRST SOLID-STATE STRUCTURE OF A CALIX[4]RESORCINARENE WITH UNDERIVATIZED HYDROXY-GROUPS [J].

LEIGH, DA ;

LINNANE, P ;

PRITCHARD, RG ;

JACKSON, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) :389-390

[9]

MCADAMS ET, 1995, BIOSENS BIOELECTRON, V10, P1429

[10] Thin sensitive organic membranes on selective iron-ion sensors [J].

Mlika, R ;

Ben Ouada, H ;

Kalfat, R ;

Gamoudi, G ;

Mhenni, F ;

Jaffrezic-Renault, N .

SYNTHETIC METALS, 1997, 90 (03) :239-243