A long-standing structural puzzle resolved:: the crystal structure of [Ag2(TpMe,Me)2] [where TpMe,Me is hydrotris(3,5-dimethyl-pyrazolyl)borate]

被引：20

作者：

Humphrey, ER ^{[1
]}

Reeves, Z ^{[1
]}

Jeffery, JC ^{[1
]}

McCleverty, JA ^{[1
]}

Ward, MD ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

POLYHEDRON | 1999年 / 18卷 / 8-9期

基金：

英国工程与自然科学研究理事会;

关键词：

hydrotris(3,5-dimethylpyrazolyl)borate; silver(I) complexes; tris(pyrazolyl)borate complexes;

D O I：

10.1016/S0277-5387(98)00443-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of the simple 1:1 complex of Ag(I) with hydrotris(3,5-dimethylpyrazolyl)borate orate (Tp(Me,Me)) has been shown to be an asymmetric dimer, in which each Tp(Me,Me) ligand bridges both metals by coordinating two pyrazolyl donors to one Ag(I) centre and one to the other, such that to a first approximation one Ag(I) is four coordinate and the other is two coordinate. However two of the pyrazolyl donors around the 'four-coordinate' metal centres are also involved in weak, asymmetric bridging interactions with the l'two coordinate' metal centres. This is in contrast to the structure of the Cu(I) analogue [Cu-2(Tp(Me,Me))(2)] in which both Cu(I) ions are three coordinate. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1335 / 1338

页数：4

共 18 条

[1] CRYSTAL-STRUCTURES OF SILVER(I) AND THALLIUM(I) COMPLEXES OF TRIS[3-(2-PYRIDYL)-PYRAZOL-1-YL]BORATE - ENCAPSULATION OF EITHER A SINGLE THALLIUM(I) ION OR TRINUCLEAR SILVER(I) CLUSTER BY A HEXADENTATE PODAND [J].

AMOROSO, AJ ;

JEFFERY, JC ;

JONES, PL ;

MCCLEVERTY, JA ;

PSILLAKIS, E ;

WARD, MD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (11) :1175-1176

[2] CRYSTAL-STRUCTURE OF 2-SULFANILAMIDOPYRIMIDINESILVER(I) [J].

BAENZIGER, NC ;

STRUSS, AW .

INORGANIC CHEMISTRY, 1976, 15 (08) :1807-1809

[3] CHEMISTRY OF THE GROUP 1B ELEMENTS .8. COMPLEXES OF COPPER(I) OR SILVER(I) CONTAINING ONLY POLY(PYRAZOLYL)BORATE LIGANDS [J].

BRUCE, MI ;

WALSH, JD .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1979, 32 (12) :2753-2756

[4] SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND ELECTROCHEMICAL-BEHAVIOR OF COPPER(I) COMPLEXES OF STERICALLY HINDERED TRIS(3-TERT-BUTYLPYRAZOLYL AND 3,5-DIPHENYLPYRAZOLYL)HYDROBORATE LIGANDS [J].

CARRIER, SM ;

RUGGIERO, CE ;

HOUSER, RP ;

TOLMAN, WB .

INORGANIC CHEMISTRY, 1993, 32 (22) :4889-4899

[5] Synthesis and chemistry of [hydrotris(3,5-bis(trifluoromethyl)pyrazolyl)borato]silver(I) complexes [J].

Dias, HVR ;

Wang, ZY ;

Jin, WC .

INORGANIC CHEMISTRY, 1997, 36 (27) :6205-6215

[6] Monomeric indium(I) and silver(I) complexes of a polyfluorinated tris(pyrazolyl)borate [J].

Dias, HVR ;

Jin, WC .

INORGANIC CHEMISTRY, 1996, 35 (01) :267-268

[7] UNSTABLE INTERMEDIATES .190. SILVER(I) IMIDAZOLE PERCHLORATE - AN (AG+)6 CLUSTER AND ITS RADIOLYTICALLY PRODUCED ONE-ELECTRON ADDUCT STUDIED BY X-RAY-DIFFRACTION AND ELECTRON-SPIN RESONANCE SPECTROSCOPY [J].

EASTLAND, GW ;

MAZID, MA ;

RUSSELL, DR ;

SYMONS, MCR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (09) :1682-1687

[8] 1,3-BIS(4-FLUORPHENYL)TRIAZENIDO COMPLEXES OF COPPER AND SILVER - SYNTHESIS AND STRUCTURE OF [CU(F-C6H4N3C6H4-F)]4, [AG(F-C6H4N3C6H4-F)]4, AND [CU(F-C6H4N3C6H4-F)(OCH3)]4 [J].

HARTMANN, E ;

STRAHLE, J .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1990, 583 (04) :31-40

[9] An unprecedented trinucleating bridging mode (μ3-η1:η1:η1) of a tris(pyrazolyl)borate ligand in a trinuclear silver(I) complex [J].

Humphrey, ER ;

Harden, NC ;

Rees, LW ;

Jeffery, JC ;

McCleverty, JA ;

Ward, MD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (20) :3353-3354

[10] SYNTHESIS AND REACTIVITY OF THE 1ST AG(I) PERTHIOCARBOXYLATES - CRYSTAL-STRUCTURES OF TETRA(ORTHO-TOLYLPERTHIOCARBOXYLATO)TETRA-SILVER(I), [AGS3C-ORTHO-TOLYL]4, AND OF ITS COCRYSTALLIZATION PRODUCT WITH COPPER(I), [AG1.76CU2.24(S3C-ORTHO-TOLYL)4] [J].

MARSICH, N ;

PELLIZER, G ;

CAMUS, A ;

LANFREDI, AMM ;

UGOZZOLI, F .

INORGANICA CHIMICA ACTA, 1990, 169 (02) :171-179

← 1 2 →