Studies on transition-metal nitrido and oxo complexes.: Part 20.: Oxoruthenates and oxo-osmates in oxidation catalysis;: cis-[Os(OH)2O4]2- as a catalytic oxidant for primary amines and for alcohols

被引：21

作者：

Griffith, WP ^{[1
]}

Suriaatmaja, M ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2001年 / 79卷 / 5-6期

关键词：

oxidation catalysis; ruthenium; osmium; amine dehydrogenation; alcohol oxidation;

D O I：

10.1139/cjc-79-5-6-598

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

cis-[Os(OH)(2)O-4](2-) with [Fe(CN)(6)](3-) and other co-oxidants has been studied as a catalytic reagent for the oxidative dehydrogenation of primary aromatic and aliphatic amines to nitriles, the oxidation of primary alcohols to carboxylic acids and of secondary alcohols to ketones. Electronic and Raman spectroscopy have been used to elucidate the nature of the oxoruthenates and oxo-osmates present in a number of reported organic oxidations catalyzed by ruthenium and osmium species.

引用

页码：598 / 606

页数：9

共 55 条

[1]

AGRAWAL MC, 1983, J SCI IND RES INDIA, V42, P508

[2]

AYODELE JT, 1996, GHANA J CHEM, V2, P57

[3]

Bailey A., 1996, J CHEM SOC CHEM COMM, P2343

[4] STUDIES ON TRANSITION-METAL OXO AND NITRIDO COMPLEXES .13. PERRUTHENATE AND RUTHENATE ANIONS AS CATALYTIC ORGANIC OXIDANTS [J].

BAILEY, AJ ;

GRIFFITH, WP ;

MOSTAFA, SI ;

SHERWOOD, PA .

INORGANIC CHEMISTRY, 1993, 32 (03) :268-271

[5] Oxo osmium(VIII) complexes in oxidation: crystal structures of OsO4 center dot nmo (nmo=N-methylmorpholine N-oxide) and OsO4 center dot nmm (nmm=N-methylmorpholine), and use of cis-[OsO4(OH)2](2-) as an oxidation catalyst [J].

Bailey, AJ ;

Bhowon, MG ;

Griffith, WP ;

Shoair, AGF ;

White, AJP ;

Williams, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (18) :3245-3250

[6] Ozonolysis for the preparation of high oxidation-state transition-metal complexes and the crystal structure of [PPh4]2[Ru2O(μ-OCOEt)2Cl6] [J].

Bailey, AJ ;

Griffith, WP ;

Marsden, SP ;

White, AJP ;

Williams, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (21) :3673-3677

[7] Studies on transition metal nitrido and oxo complexes .16(1). The nature of the oxoruthenates involved in some ruthenium-catalysed organic oxidations [J].

Bailey, AJ ;

Cother, LD ;

Griffith, WP ;

Hankin, DM .

TRANSITION METAL CHEMISTRY, 1995, 20 (06) :590-594

[8]

BAILEY AJ, 1997, J CHEM SOC CHEM COMM, P507

[9]

BRAHMAIAH A, 1995, INDIAN J CHEM A, V34, P900

[10]

Brahmaiah A, 1996, OXID COMMUN, V19, P94

← 1 2 3 4 5 6 →