Characterization of thermally reduced graphene oxide by imaging ellipsometry

被引:197
作者
Jung, Inhwa [1 ]
Vaupel, Matthias [2 ]
Pelton, Matthew [3 ]
Piner, Richard [1 ]
Dikin, Drnitriy A. [4 ]
Stankovich, Sasha [4 ]
An, Jinho [1 ]
Ruoff, Rodney S. [1 ]
机构
[1] Univ Texas Austin, Dept Mech Engn, Austin, TX 78712 USA
[2] Nanofilm Technol GmbH, D-37081 Gottingen, Germany
[3] Argonne Natl Lab, Ctr Nanoscale Mat, Argonne, IL 60439 USA
[4] Northwestern Univ, Dept Mech Engn, Evanston, IL 60208 USA
关键词
D O I
10.1021/jp802173m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dispersion functions for the refractive index and the extinction coefficient of single- and multiple-layer graphene oxide samples were measured by imaging spectroscopic ellipsometry in the wavelength range of 350-1000 nm and were compared to previously reported results measured by confocal microscopy. The dispersion functions for thin platelets were also compared to those obtained by standard spectroscopic ellipsometry on a deposit consisting of many overlapping graphene oxide layers. Changes were observed in both the thickness of the deposits and the values of the dispersion parameters following heating. A model is proposed to explain these observations, based on the removal of water between the graphene-oxide layers upon thermal treatment.
引用
收藏
页码:8499 / 8506
页数:8
相关论文
共 29 条
  • [1] [Anonymous], 1994, The Optical Constants of Bulk Materials and Films
  • [2] Azzam R.M.A., 1977, Ellipsometry and Polarized Light
  • [3] PERFORMANCE OF A MICROSCOPIC IMAGING ELLIPSOMETER
    BEAGLEHOLE, D
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1988, 59 (12) : 2557 - 2559
  • [4] Making graphene visible
    Blake, P.
    Hill, E. W.
    Castro Neto, A. H.
    Novoselov, K. S.
    Jiang, D.
    Yang, R.
    Booth, T. J.
    Geim, A. K.
    [J]. APPLIED PHYSICS LETTERS, 2007, 91 (06)
  • [5] Preparation and characterization of graphene oxide paper
    Dikin, Dmitriy A.
    Stankovich, Sasha
    Zimney, Eric J.
    Piner, Richard D.
    Dommett, Geoffrey H. B.
    Evmenenko, Guennadi
    Nguyen, SonBinh T.
    Ruoff, Rodney S.
    [J]. NATURE, 2007, 448 (7152) : 457 - 460
  • [6] Optical properties of graphite
    Djurisic, AB
    Li, EH
    [J]. JOURNAL OF APPLIED PHYSICS, 1999, 85 (10) : 7404 - 7410
  • [7] EDA G, 2008, NAT NANOTECHNOL, V83, DOI DOI 10.1038/NNAN0
  • [8] ELHAIJA AJA, 2003, J APPL PHYS, V93, P5
  • [9] A chemical route to graphene for device applications
    Gilje, Scott
    Han, Song
    Wang, Minsheng
    Wang, Kang L.
    Kaner, Richard B.
    [J]. NANO LETTERS, 2007, 7 (11) : 3394 - 3398
  • [10] Electronic transport properties of individual chemically reduced graphene oxide sheets
    Gomez-Navarro, Cristina
    Weitz, R. Thomas
    Bittner, Alexander M.
    Scolari, Matteo
    Mews, Alf
    Burghard, Marko
    Kern, Klaus
    [J]. NANO LETTERS, 2007, 7 (11) : 3499 - 3503