Channel-facilitated molecule and ion transport across polymer composite membranes

被引：114

作者：

Cao, Li ^{[1
,2
]}

He, Xueyi ^{[1
,2
]}

Jiang, Zhongyi ^{[1
,2
]}

Li, Xueqin ^{[3
]}

Li, Yifan ^{[4
]}

Ren, Yanxiong ^{[1
,2
]}

Yang, Leixin ^{[1
,2
]}

Wu, Hong ^{[1
,2
,5
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, Minist Educ, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China

[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China

[3] Shihezi Univ, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Sch Chem & Chem Engn, Shihezi 832003, Xinjiang, Peoples R China

[4] Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China

[5] Tianjin Univ, Tianjin Key Lab Membrane Sci & Desalinat Technol, Tianjin 300072, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2017年 / 46卷 / 22期

基金：

中国国家自然科学基金; 国家重点研发计划;

关键词：

PROTON TRANSPORT; EXCHANGE MEMBRANES; PROTOGENIC GROUP; PHOSPHONIC ACID; SULFONIC-ACID; LOW HUMIDITY; GRAPHENE; CO2; IMIDAZOLE; PERFORMANCE;

D O I：

10.1039/c5cs00906e

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Biological membranes possess hierarchical channels and thus exhibit ultrahigh permselectivity for molecules and ions. Intrigued by the delicate structure and transport mechanisms in biochannels, polymer composite membranes with selective transport channels are successfully fabricated for diverse energy- and environment-related applications. This tutorial review aims to present the latest progress in the design and construction of selective molecule/ion transport channels within polymer composite membranes with emphasis on the regulation of the physical and chemical microenvironments of these channels. The concluding remarks are presented with a tentative perspective on the future research and development of highly efficient channel-facilitated molecule/ion transport across polymer composite membranes.

引用

页码：6725 / 6745

页数：21

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[1]

THE GROTTHUSS MECHANISM [J].