Two new monoterpene glycosides and a new (+)-jasmololone glucoside from Bidens parviflora Willd

被引:15
作者
Wang, Nai-Li
Wang, Jue
Yao, Xin-Sheng
Kitanaka, Susumu
机构
[1] Nihon Univ, Coll Pharm, Chiba 2748555, Japan
[2] Shenyang Pharmaceut Univ, Dept Nat Prod Chem, Shenyang 110015, Peoples R China
关键词
Bidens parviflora Willd; (1S; 3S; 4R)-3-hydroxy-p-menth-6-one; 3-O-beta-D-glucopyranoside; (3R; 4R)-3-hydroxy-p-menth-1(2)-en-6-one; (+)-Jasmololone glucoside; CD analysis; radical scavenger;
D O I
10.1080/10286020500532033
中图分类号
Q94 [植物学];
学科分类号
071001 [植物学];
摘要
Two new monoterpene glycosides named bidensmenthosides A, B and a new (+)-jasmololone glucoside, were isolated from the air-dried whole plant of Bidens parviflora Willd. Their structures were determined as ( 1S, 3S, 4R)-3-hydroxy-p-menth-6-one3-O-beta-D-glucopyranoside (1), (3R, 4R)-3-hydroxy- p- menth- 1 ( 2)-en-6-one 3-O-beta-D-glucopyranoside (2) and (4R)- hydroxy-3-methyl-2-(2 Z- pentenyl)-cyclopent-2enone 4-O-beta-D-glucopyranoside (3) based on spectroscopic analysis and physiochemical properties, respectively. The bidensmenthosides A, B and aglycone of 3 were found to reduce 2, 2- diphenyl- 1-picrylhydrazyl ( DPPH) radicals.
引用
收藏
页码:449 / 455
页数:7
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