Controlled synthesis of bismuth oxo nanoscale crystals (BiOCl, Bi12O17Cl2, α-Bi2O3, and (BiO)2CO3) by solution-phase methods

被引：67

作者：

Chen, Xiang Ying ^{[1
]}

Huh, Hyun Sue ^{[1
]}

Lee, Soon W. ^{[1
]}

机构：

[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2007年 / 180卷 / 09期

关键词：

bismuth compounds; solution-phase; nanostructures; photoluminescence;

D O I：

10.1016/j.jssc.2007.06.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We present the controlled solution-phase synthesis of several sheet- or rod-like bismuth oxides, BiOCl, Bi12O17Cl2, alpha-Bi2O3 and (BiO)(2)CO3, by adjusting growth parameters such as reaction temperature, mole ratios of reactants, and the base used. BiOCl, Bi12O17Cl2, and alpha-Bi2O3 could be prepared from BiCl3 and NaOH, whereas (BiO)(2)CO3 was prepared from BiCl3 and urea. BiOCI and Bi12O17Cl2 could also be prepared from BiCl3 and ammonia. The alpha-Bi2O3 sample exhibited strong emission at room temperature. (c) 2007 Elsevier Inc. All rights reserved.

引用

页码：2510 / 2516

页数：7

共 25 条

[11] Conversion of a Bi nanowire array to an array of Bi-Bi2O3 core-shell nanowires and Bi2O3 nanotubes [J].

Li, L ;

Yang, YW ;

Li, GH ;

Zhang, LD .

SMALL, 2006, 2 (04) :548-553

[12]

Nurgalicv B. Z., 1985, RUSS J INORG CHEM, V30, P948

[13] Synthesis, optical properties, and self-assembly of ultrathin hexagonal In2S3 nanoplates [J].

Park, Kang Hyun ;

Jang, Kwonho ;

Son, Seung Uk .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (28) :4608-4612

[14] Synthesis of bismuth oxide nanoparticles at 100 °C [J].

Patil, MM ;

Deshpande, VV ;

Dhage, SR ;

Ravi, V .

MATERIALS LETTERS, 2005, 59 (19-20) :2523-2525

[15] Controlled synthesis of bismuth oxide nanowires by an oxidative metal vapor transport deposition technique [J].

Qiu, Yongfu ;

Liu, Dongfang ;

Yang, Jinhu ;

Yang, Shihe .

ADVANCED MATERIALS, 2006, 18 (19) :2604-+

[16] Coordination chemistry of metals in medicine: target sites for bismuth [J].

Sadler, PJ ;

Li, HY ;

Sun, HZ .

COORDINATION CHEMISTRY REVIEWS, 1999, 185-6 :689-709

[17] Oxide ion conducting solid electrolytes based on Bi2O3 [J].

Shuk, P ;

Wiemhofer, HD ;

Guth, U ;

Gopel, W ;

Greenblatt, M .

SOLID STATE IONICS, 1996, 89 (3-4) :179-196

[18] Halide CVD of Bi2O3 under atmospheric pressure:: Synthesis of α-rods and δ-films [J].

Takeyama, Tomoharu ;

Kajikawa, Yuya ;

Takahashi, Naoyuki ;

Nakamura, Takato ;

Itoh, Setsuro .

CHEMICAL VAPOR DEPOSITION, 2006, 12 (04) :203-206

[19] Synthesis of single-crystalline nanobelts of ternary bismuth oxide bromide with different compositions [J].

Wang, JW ;

Li, YD .

CHEMICAL COMMUNICATIONS, 2003, (18) :2320-2321

[20] One-dimensional nanostructures: Synthesis, characterization, and applications [J].

Xia, YN ;

Yang, PD ;

Sun, YG ;

Wu, YY ;

Mayers, B ;

Gates, B ;

Yin, YD ;

Kim, F ;

Yan, YQ .

ADVANCED MATERIALS, 2003, 15 (05) :353-389

← 1 2 3 →