The kinetics of mixing and the fluctuation theorem in ideal mixtures of two-component model fluids

被引：5

作者：

Baranyai, A ^{[1
]}

机构：

[1] Eotvos Lorand Univ, Dept Theoret Chem, H-1518 Budapest 112, Hungary

来源：

JOURNAL OF CHEMICAL PHYSICS | 2003年 / 119卷 / 04期

关键词：

D O I：

10.1063/1.1585015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using a simple combinatorial model we show that the fluctuation theorem holds for the nonequilibrium transient process of mixing in ideal mixtures of two-component fluids. We show that the fluctuation theorem is very closely connected to the phenomenological formalism of reaction kinetics, in particular, to unimolecular reactions. (C) 2003 American Institute of Physics.

引用

页码：2144 / 2146

页数：3

共 7 条

[1] A local fluctuation theorem [J].

Ayton, G ;

Evans, DJ ;

Searles, DJ .

JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (05) :2033-2037

[2] PROBABILITY OF 2ND LAW VIOLATIONS IN SHEARING STEADY-STATES [J].

EVANS, DJ ;

COHEN, EGD ;

MORRISS, GP .

PHYSICAL REVIEW LETTERS, 1993, 71 (15) :2401-2404

[3] The fluctuation theorem [J].

Evans, DJ ;

Searles, DJ .

ADVANCES IN PHYSICS, 2002, 51 (07) :1529-1585

[4] Fluctuation theorem for Hamiltonian systems: Le Chatelier's principle [J].

Evans, DJ ;

Searles, DJ ;

Mittag, E .

PHYSICAL REVIEW E, 2001, 63 (05)

[5] DYNAMICAL ENSEMBLES IN NONEQUILIBRIUM STATISTICAL-MECHANICS [J].

GALLAVOTTI, G ;

COHEN, EGD .

PHYSICAL REVIEW LETTERS, 1995, 74 (14) :2694-2697

[6]

van Kampen N. G., 1984, ESSAYS THEORETICAL P, P303

[7] Experimental demonstration of violations of the second law of thermodynamics for small systems and short time scales [J].

Wang, GM ;

Sevick, EM ;

Mittag, E ;

Searles, DJ ;

Evans, DJ .

PHYSICAL REVIEW LETTERS, 2002, 89 (05)

← 1 →