Two-step kinetics of As/P exchange reaction

被引:7
作者
Suh, KY
Lee, HH [1 ]
Yoon, E
机构
[1] Seoul Natl Univ, Sch Chem Engn, Seoul 151742, South Korea
[2] Seoul Natl Univ, Nanoelect Inst, Seoul 151742, South Korea
[3] Seoul Natl Univ, Sch Mat Sci & Engn, Seoul 151742, South Korea
关键词
D O I
10.1063/1.369433
中图分类号
O59 [应用物理学];
学科分类号
摘要
A simple two-step mechanism is used to derive the kinetics of the As/P exchange reaction which takes place on an epitaxially grown InP surface exposed to As flux. The first step involves surface exchange of arsenic with phosphorus, which is then followed by the second step, bulk exchange of arsenic (arsenic incorporation). Two possible choices are investigated for bulk exchange: the same exchange rate constant in the bulk and the same ratio of exchange rate constants in the bulk. Transient and steady-state profiles of As composition and the maximum depth of the As/P exchange reaction are derived analytically. (C) 1999 American Institute of Physics. [S0021-8979(99)04601-0].
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页码:233 / 236
页数:4
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