Formation of CuInSe2 and Cu(In,Ga)Se2 films by electrodeposition and vacuum annealing treatment

被引：55

作者：

Zhang, L ^{[1
]}

Jiang, FD ^{[1
]}

Feng, JY ^{[1
]}

机构：

[1] Tsing Hua Univ, Dept Mat Sci & Engn, Natl Tribiol Lab, Beijing 100084, Peoples R China

来源：

SOLAR ENERGY MATERIALS AND SOLAR CELLS | 2003年 / 80卷 / 04期

关键词：

CuInSe2; Cu(In; Ga)Se-2; electrodeposition; annealing treatment; thin films;

D O I：

10.1016/j.solmat.2003.06.014

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Polycrystalline thin films of CuInSe2 and Cu(In,Ga)Se-2 (CIGS) were grown on both polished Mo substrates and Mo-coated glass substrates by one-step electrodeposition. All the as-deposited films have been annealed in vacuum at 450degreesC for a short time to improve the crystalline properties. The films have been characterized by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray analysis. The results indicate that the crystallization of the films was greatly improved after annealing. Further more, a CIGS film with 23 at% Ga was obtained. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：483 / 490

页数：8

共 14 条

[1] 15.4% CuIn1-xGaxSe2-based photovoltaic cells from solution-based precursor films [J].

Bhattacharya, RN ;

Hiltner, JF ;

Batchelor, W ;

Contreras, MA ;

Noufi, RN ;

Sites, JR .

THIN SOLID FILMS, 2000, 361 :396-399

[2]

Bodegard M., 1995, P 13 EUR PHOT SOL EN, P2080

[3] Electro/electroless deposition and characterization of Cu-In precursors for CIS (CuInSe2) films [J].

Calixto, E ;

Sebastian, PJ ;

Fernandez, A .

JOURNAL OF CRYSTAL GROWTH, 1996, 169 (02) :287-292

[4] Electrodeposition of CuInxGa1-xSe2 thin films [J].

Friedfeld, R ;

Raffaelle, RP ;

Mantovani, JG .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1999, 58 (04) :375-385

[5] One, step electrodeposition of CuInSe2: Improved structural, electronic, and photovoltaic properties by annealing under high selenium pressure [J].

Guillemoles, JF ;

Cowache, P ;

Lusson, A ;

Fezzaa, K ;

Boisivon, F ;

Vedel, J ;

Lincot, D .

JOURNAL OF APPLIED PHYSICS, 1996, 79 (09) :7293-7302

[6] Low-cost deposition of CuInSe2 (CIS) films for CdS/CIS solar cells [J].

Hermann, AM ;

Westfall, R ;

Wind, R .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1998, 52 (3-4) :355-360

[7] Deposition of smooth Cu(In,Ga)Se2 films from binary multilayers [J].

Hermann, AM ;

Mansour, M ;

Badri, V ;

Pinkhasov, B ;

Gonzales, C ;

Fickett, F ;

Calixto, ME ;

Sebastian, PJ ;

Marshall, CH ;

Gillespie, TJ .

THIN SOLID FILMS, 2000, 361 :74-78

[8] Large area electrodeposition of Cu(In,Ga)Se2 [J].

Kampmann, A ;

Sittinger, V ;

Rechid, J ;

Reineke-Koch, R .

THIN SOLID FILMS, 2000, 361 :309-313

[9] PREPARATION OF DEVICE-QUALITY CU(IN,GA)SE-2 THIN-FILMS DEPOSITED BY COEVAPORATION WITH COMPOSITION MONITOR [J].

KOHARA, N ;

NEGAMI, T ;

NISHITANI, M ;

WADA, T .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1995, 34 (9A) :L1141-L1144

[10] Phases, morphology, and diffusion in CuInxGa1-xSe2 thin films [J].

Marudachalam, M ;

Birkmire, RW ;

Hichri, H ;

Schultz, JM ;

Swartzlander, A ;

AlJassim, MM .

JOURNAL OF APPLIED PHYSICS, 1997, 82 (06) :2896-2905

← 1 2 →