Hole and Electron Extraction Layers Based on Graphene Oxide Derivatives for High-Performance Bulk Heterojunction Solar Cells

被引:283
作者
Liu, Jun [1 ]
Xue, Yuhua [1 ,2 ]
Gao, Yunxiang [1 ]
Yu, Dingshan [1 ]
Durstock, Michael [3 ]
Dai, Liming [1 ]
机构
[1] Case Western Reserve Univ, Case Sch Engn, Dept Macromol Sci & Engn, Ctr Adv Sci & Engn Carbon Case4Carbon, Cleveland, OH 44106 USA
[2] Wenzhou Med Coll, Sch Ophthalmol & Optometry, Inst Adv Mat Nanobio Applicat, Zhejiang 325027, Peoples R China
[3] USAF, Res Lab, RXBP, Mat & Mfg Directorate, Wright Patterson AFB, OH 45433 USA
基金
美国国家科学基金会;
关键词
bulk heterojunction solar cells; graphene oxides; charge extraction; cesium; functionalization; POLYMER PHOTOVOLTAIC CELLS; CARBON; DONOR; FILMS;
D O I
10.1002/adma.201104945
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By charge neutralization of carboxylic acid groups in graphene oxide (GO) with Cs 2CO 3 to afford Cesium-neutralized GO (GO-Cs), GO derivatives with appropriate modification are used as both hole- and electron-extraction layers for bulk heterojunction (BHJ) solar cells. The normal and inverted devices based on GO hole- and GO-Cs electron-extraction layers both outperform the corresponding standard BHJ solar cells. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2228 / 2233
页数:6
相关论文
共 40 条
[1]   Honeycomb Carbon: A Review of Graphene [J].
Allen, Matthew J. ;
Tung, Vincent C. ;
Kaner, Richard B. .
CHEMICAL REVIEWS, 2010, 110 (01) :132-145
[2]   Dithienogermole As a Fused Electron Donor in Bulk Heterojunction Solar Cells [J].
Amb, Chad M. ;
Chen, Song ;
Graham, Kenneth R. ;
Subbiah, Jegadesan ;
Small, Cephas E. ;
So, Franky ;
Reynolds, John R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (26) :10062-10065
[3]  
[Anonymous], ADV MAT
[4]   Large-Area Graphene Films by Simple Solution Casting of Edge-Selectively Functionalized Graphite [J].
Bae, Seo-Yoon ;
Jeon, In-Yup ;
Yang, Jieun ;
Park, Noejung ;
Shin, Hyeon Suk ;
Park, Sungjin ;
Ruoff, Rodney S. ;
Dai, Liming ;
Baek, Jong-Beom .
ACS NANO, 2011, 5 (06) :4974-4980
[5]  
Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/nnano.2010.132, 10.1038/NNANO.2010.132]
[6]   Cesium carbonate as a functional interlayer for polymer photovoltaic devices [J].
Chen, Fang-Chung ;
Wu, Jyh-Lih ;
Yang, Sidney S. ;
Hsieh, Kuo-Huang ;
Chen, Wen-Chang .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (10)
[7]   High-efficiency inverted solar cells based on a low bandgap polymer with excellent air stability [J].
Chu, Ta-Ya ;
Tsang, Sai-Wing ;
Zhou, Jiayun ;
Verly, Pierre G. ;
Lu, Jianping ;
Beaupre, Serge ;
Leclerc, Mario ;
Tao, Ye .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 96 (01) :155-159
[8]   Bulk Heterojunction Solar Cells Using Thieno[3,4-c]pyrrole-4,6-dione and Dithieno[3,2-b:2′,3′-d]silole Copolymer with a Power Conversion Efficiency of 7.3% [J].
Chu, Ta-Ya ;
Lu, Jianping ;
Beaupre, Serge ;
Zhang, Yanguang ;
Pouliot, Jean-Remi ;
Wakim, Salem ;
Zhou, Jiayun ;
Leclerc, Mario ;
Li, Zhao ;
Ding, Jianfu ;
Tao, Ye .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (12) :4250-4253
[9]   The chemistry of graphene oxide [J].
Dreyer, Daniel R. ;
Park, Sungjin ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240
[10]   Chemically Derived Graphene Oxide: Towards Large-Area Thin-Film Electronics and Optoelectronics [J].
Eda, Goki ;
Chhowalla, Manish .
ADVANCED MATERIALS, 2010, 22 (22) :2392-2415