One- and two-dimensional framework materials constructed from the mixed Mo/V tetra-capped Keggin structure clusters and M(en)2 (M = Ni, Cu) complexes groups

被引：55

作者：

Bu, WM

Ye, L

Yang, GY

Gao, JS

Fan, YG ^{[1
]}

Shao, MC

Xu, JQ

机构：

[1] Jilin Univ, Key Lab Supermol Struct & Spect, Changchun 130023, Peoples R China

[2] Heilongjing Univ, Dept Chem, Harbin, Peoples R China

[3] Peking Univ, Dept Chem, Beijing 100871, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 01期

关键词：

crystal structures; one- and two-dimensional frameworks; the mixed Mo/V tetra-capped Keggin structure clusters; linked through M(en)(2)(M = Ni; Cu); groups;

D O I：

10.1016/S1387-7003(00)00179-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel low-dimensional framework materials, [Ni(en)(2)](2)[Ni(en)(2)(Mo6V10O40)-V-VI-O-VI((VO4)-O-IV)] . 4H(2)O (1) and [en](0.5)[Cu(en)(2)](2)[Cu(en)(2)(Mo6Mo2V8O40)-Mo-VI-V-V-O-IV((MoO4)-O-IV)] . 0.5H(2)O (2), assembled hydrothermally, are constructed from the mixed Mo/V tetra-capped Keggin structure clusters linked through M(en)(2)(M = Ni, Cu) groups. (C) 2001 Published by Elsevier Science B.V. All rights reserved.

引用

页码：1 / 4

页数：4

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[3]

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