Ambipolarity in Benzobisthiadiazole-Based Donor-Acceptor Conjugated Polymers

被引：121

作者：

Yuen, Jonathan D. ^{[1
]}

Kumar, Rajeev ^{[2
]}

Zakhidov, Dante ^{[1
]}

Seifter, Jason ^{[1
]}

Lim, Bogyu ^{[1
]}

Heeger, Alan J. ^{[1
]}

Wudl, Fred ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA

[2] Nanoterra Inc, Brighton, MA 02135 USA

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 33期

基金：

美国国家科学基金会;

关键词：

FIELD-EFFECT TRANSISTORS; LOW-BANDGAP; N-CHANNEL; DIKETOPYRROLOPYRROLE; SEMICONDUCTORS; POLYTHIOPHENES; COPOLYMERS; TRANSPORT; ELECTRON;

D O I：

10.1002/adma.201101134

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A family of four new DA polymers, in which the acceptor moiety benzobisthiadiazole was paired with four different donor moieties, has been synthesized. Surprisingly, all members of the family exhibit balanced ambipolar behavior, despite polymer to polymer mobilities varying from 10(-4) cm(2) V-1 s(-1) to 10(-1) cm(2) V-1 s(-1). Applications in single component CMOS integrated circuits are envisioned.

引用

页码：3780 / +

页数：7

共 32 条

[1] Organic semiconductors for solution-processable field-effect transistors (OFETs) [J].

Allard, Sybille ;

Forster, Michael ;

Souharce, Benjamin ;

Thiem, Heiko ;

Scherf, Ullrich .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (22) :4070-4098

[2] Organic complementary-like inverters employing methanofullerene-based ambipolar field-effect transistors [J].

Anthopoulos, TD ;

de Leeuw, DM ;

Cantatore, E ;

Setayesh, S ;

Meijer, EJ ;

Tanase, C ;

Hummelen, JC ;

Blom, PWM .

APPLIED PHYSICS LETTERS, 2004, 85 (18) :4205-4207

[3] Air-stable complementary-like circuits based on organic ambipolar transistors [J].

Anthopoulos, Thomas D. ;

Setayesh, Sepas ;

Smits, Edsger ;

Colle, Michael ;

Cantatore, Eugenio ;

de Boer, Bert ;

Blom, Paul W. M. ;

de Leeuw, Dago M. .

ADVANCED MATERIALS, 2006, 18 (14) :1900-+

[4] Efficient Solar Cells Based on an Easily Accessible Diketopyrrolopyrrole Polymer [J].

Bijleveld, Johan C. ;

Gevaerts, Veronique S. ;

Di Nuzzo, Daniele ;

Turbiez, Mathieu ;

Mathijssen, Simon G. J. ;

de Leeuw, Dago M. ;

Wienk, Martijn M. ;

Janssen, Rene A. J. .

ADVANCED MATERIALS, 2010, 22 (35) :E242-+

[5] Poly(diketopyrrolopyrrole-terthiophene) for Ambipolar Logic and Photovoltaics [J].

Bijleveld, Johan C. ;

Zoombelt, Arjan P. ;

Mathijssen, Simon G. J. ;

Wienk, Martijn M. ;

Turbiez, Mathieu ;

de Leeuw, Dago M. ;

Janssen, Rene A. J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (46) :16616-+

[6] High-mobility ambipolar near-infrared light-emitting polymer field-effect transistors [J].

Buergi, Lukas ;

Turbiez, Mathieu ;

Pfeiffer, Reto ;

Bienewald, Frank ;

Kirner, Hans-Joerg ;

Winnewisser, Carsten .

ADVANCED MATERIALS, 2008, 20 (11) :2217-2224

[7] High Mobility Ambipolar Charge Transport in Polyselenophene Conjugated Polymers [J].

Chen, Zhuoying ;

Lemke, Henrik ;

Albert-Seifried, Sebastian ;

Caironi, Mario ;

Nielsen, Martin Meedom ;

Heeney, Martin ;

Zhang, Weimin ;

McCulloch, Iain ;

Sirringhaus, Henning .

ADVANCED MATERIALS, 2010, 22 (21) :2371-2375

[8] General observation of n-type field-effect behaviour in organic semiconductors [J].

Chua, LL ;

Zaumseil, J ;

Chang, JF ;

Ou, ECW ;

Ho, PKH ;

Sirringhaus, H ;

Friend, RH .

NATURE, 2005, 434 (7030) :194-199

[9] Organic Transistors in Optical Displays and Microelectronic Applications [J].

Gelinck, Gerwin ;

Heremans, Paul ;

Nomoto, Kazumasa ;

Anthopoulos, Thomas D. .

ADVANCED MATERIALS, 2010, 22 (34) :3778-3798

[10] Conjugated Polymers from Naphthalene Bisimide [J].

Guo, Xugang ;

Watson, Mark D. .

ORGANIC LETTERS, 2008, 10 (23) :5333-5336

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